Synthesis and properties of highly photoluminescent and electrochemically active polymers containing 2-pyrazoline units in the main chain

被引：5

作者：

Fang, Q ^{[1
]}

Jiang, B ^{[1
]}

Xu, B ^{[1
]}

Cao, AM ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 21期

关键词：

electrochemical properties; optical properties; photolummescent polymer; polycondensation; pyrazoline derivatives;

D O I：

10.1002/marc.200400353

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new polymers containing 2-pyrazoline units in the main chain were synthesized for the first time by a Suzuki polycondensation between a 2-pyrazoline monomer and aryl diboronic esters. The polymers showed high photoluminescence (PL) in both the solution and the solid state; quantum yields of PL in toluene were higher than 76%. Thermogravimetric analysis and cyclic voltammetry showed that the polymers had high thermal stability and good reversibility under electrochemical oxidation.

引用

页码：1856 / 1859

页数：4

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