NMR spectroscopic correlations for a series of triangular α-oxoruthenium acetate clusters containing substituted pyridine ligands

被引：29

作者：

Alexiou, ADP ^{[1
]}

Toma, HE ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1997年 / 09期

关键词：

D O I：

10.1039/a701058c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H-1 and C-13 NMR chemical shifts of the acetate and pyridine ligands (alpha-position) in a series of [RU3O(CH3CO2)(6)L-3](+) clusters are linearly correlated with the pK(8) (L), but exhibit variable trends at the various positions as a consequence of the inductive, paramagnetic anisotropy and ring current effects and the ligand interactions through the Ru3O core.

引用

页码：338 / 339

页数：3

共 20 条

[1] REVERSIBLE MULTISTEP AND MULTIELECTRON REDOX BEHAVIOR OF AN OXO-CENTERED TRINUCLEAR RUTHENIUM COMPLEX WITH A REDOX-ACTIVE LIGAND, [RU-3(MU(3)-O)(MU-CH3CO2)(6)(MBPY(+))(3)](4+)(MBPY(+)=N-METHYL-4,4'-BIPYRIDINIUM ION), AND ITS TRIRHODIUM AND DIRUTHENIUM-RHODIUM DERIVATIVES [J].

ABE, M ;

SASAKI, Y ;

YAMADA, Y ;

TSUKAHARA, K ;

YANO, S ;

ITO, T .

INORGANIC CHEMISTRY, 1995, 34 (17) :4490-4498

[2] KINETIC-STUDIES ON THE TERMINAL PYRIDINE EXCHANGE-REACTIONS OF SOME OXO-ACETATE BRIDGED TRINUCLEAR RUTHENIUM COMPLEXES - INFLUENCE OF THE METAL OXIDATION-STATE AND NON-LEAVING TERMINAL LIGAND (CO) [J].

ABE, M ;

SASAKI, Y ;

NAGASAWA, A ;

ITO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (05) :1411-1414

[3] X-RAY STRUCTURE, LIGAND SUBSTITUTION, AND OTHER PROPERTIES OF TRINUCLEAR RUTHENIUM COMPLEX, [RU3(MU-3-O)(MU-C6H5COO)6(PY)3](PF6) (PY=PYRIDINE), AND X-RAY STRUCTURE OF DINUCLEAR RUTHENIUM COMPLEX, [RU2(MU-C6H5COO)4CL] [J].

ABE, M ;

SASAKI, Y ;

YAMAGUCHI, T ;

ITO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (06) :1585-1590

[4] ELECTRONIC-STRUCTURE AND REDOX PROPERTIES OF CLUSTERS [RU3O(CH3CO2)6L3]N+ [J].

BAUMANN, JA ;

SALMON, DJ ;

WILSON, ST ;

MEYER, TJ ;

HATFIELD, WE .

INORGANIC CHEMISTRY, 1978, 17 (12) :3342-3350

[5] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST [J].

BILGRIEN, C ;

DAVIS, S ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3786-3787

[6]

Cotton F. A., 1972, INORGAN CHIM ACTA, V6, P411, DOI DOI 10.1016/S0020-1693(00)91829-2

[7] SYNTHESIS, CHARACTERIZATION, AND OXIDATION CATALYSIS BY A NOVEL (MU-3-OXO)TRIRUTHENIUM CARBOXYLATE COMPLEX [J].

DAVIS, S ;

DRAGO, RS .

INORGANIC CHEMISTRY, 1988, 27 (26) :4759-4760

[8] MAGNETIC AND SPECTRAL PROPERTIES OF HETEROTRINUCLEAR ACETATES [RU2CO(MU-3-O)(MU-CH3CO2)6(PY)3]N+ (N=0 OR 1) [J].

DONG, TY ;

LEE, HS ;

LEE, TY ;

HSIEH, CF .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1992, 39 (05) :393-399

[9] A SURVEY OF HAMMETT SUBSTITUENT CONSTANTS AND RESONANCE AND FIELD PARAMETERS [J].

HANSCH, C ;

LEO, A ;

TAFT, RW .

CHEMICAL REVIEWS, 1991, 91 (02) :165-195

[10] ELECTROCHEMICAL PARAMETRIZATION OF METAL-COMPLEX REDOX POTENTIALS, USING THE RUTHENIUM(III) RUTHENIUM(II) COUPLE TO GENERATE A LIGAND ELECTROCHEMICAL SERIES [J].

LEVER, ABP .

INORGANIC CHEMISTRY, 1990, 29 (06) :1271-1285

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