Synthesis, structure, magnetic, and spectroscopic properties of a chloro-bridged trinuclear copper(II) complex: {[Cu(bpea)Cl]2CuCl4}

被引：16
作者：
Qian, Jing [2 ]
Xie, Ming-Jin [3 ]
Feng, Li [4 ]
Tian, Jin-Lei [1 ]
Shang, Jing [2 ]
Zhang, Yuan [2 ]
Yan, Shi-Ping [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300387, Peoples R China
[3] Yunnan Univ, Dept Chem, Kunming 650091, Peoples R China
[4] Tianjin Univ Tradit Chinese Med, Dept Med, Tianjin 300193, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 13期
基金：
中国国家自然科学基金;
关键词：
Crystal structure; Magnetic properties; Electrochemistry; Spectroscopic properties; CRYSTAL-STRUCTURE; REACTIVITY; LIGANDS; OXIDATION; CORE;
D O I：
10.1080/00958972.2010.501862
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, a chloro-bridged trinuclear copper complex {[Cu(bpea)Cl](2)CuCl4} (1) (bpea = N,N-bis(2-pyridylmethyl)ethylamine) has been synthesized and structurally characterized. In 1, two mononuclear [Cu(bpea)Cl](+) are linked by one CuCl42- generating a sandwich-like trinuclear unit. A crystallographic C-2 axis passes through the Cu of the connecting CuCl42-. Susceptibility data of 1 indicate weak intratrimer ferromagnetic coupling with J = 5.16 cm(-1). Elemental analysis, infrared, UV spectra, and electrochemistry of the complex were also determined.
引用
收藏
页码：2239 / 2246
页数：8
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