Electromechanical probing of ionic currents in energy storage materials

被引:62
作者
Morozovska, A. N. [1 ]
Eliseev, E. A. [2 ]
Kalinin, S. V. [3 ]
机构
[1] Natl Acad Sci Ukraine, Inst Semicond Phys, UA-03028 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, Inst Problems Mat Sci, UA-03142 Kiev, Ukraine
[3] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37922 USA
关键词
bismuth compounds; cooling; domains; ferroelasticity; ferroelectric materials; ferroelectric transitions; nucleation; sodium compounds; ATOMIC-FORCE MICROSCOPY; THIN-FILMS; LICOO2; DIFFUSION; CELL;
D O I
10.1063/1.3446838
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electrochemical processes in energy storage materials are generally linked with changes of molar volume of the host compound. Here, the frequency dependent strain response of one-dimensional electrochemically active system to periodic electric bias is analyzed. The sensitivity and resolution of electrochemical strain measurements are compared to the current-based electrochemical impedance spectroscopy. The resolution and detection limits of interferometric and atomic force microscopy based systems for probing electrochemical reactions on the nanoscale are analyzed. (C) 2010 American Institute of Physics. [doi:10.1063/1.3446838]
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页数:3
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