Influence of permafrost and hydrogeology on seasonal and spatial variations in water chemistry of an alpine river in the northeastern Qinghai-Tibet Plateau, China

Known as the third pole of the world, the Qinghai-Tibet Plateau has been experiencing rapid permafrost warming and thawing over the last few decades. However, the impact of permafrost distribution and hydrogeology on river hydrochemistry in alpine areas remains unclear. This study conducted four sampling campaigns to reveal the temporal and spatial variations in and factors driving river hydrochemistry in the upper reaches of the Heihe River, the northeastern Qinghai-Tibet Plateau. We found that the concentrations of major ions and total dissolved solids (TDS) in river water showed substantial seasonal variations; the concentrations were generally lower during the initial thawing and thawed periods than during the initial freezing period. However, solute fluxes during the thawed period were much higher than those during the frozen period. The concentrations of major ions and TDS gradually decreased to a minimum from the permafrost meander (PM) section to the seasonal frost meander (SFM) section and then increased the seasonal frost canyon section. Using the revised forward model, we found that river solutes were contributed by carbonate weathering (mean 38.9%) > sulfide oxidation (22.9%) > evaporite dissolution (20.2%) > atmospheric precipitation (8.7%) > silicate weathering (5.0%) > glacial meltwater (4.3%). The higher TDS, Na+, Cl-, Ca2+, Mg2+, and SO42- concentrations in the PM section reflected the influence of freeze-out fractionation. The concentrations of major ions and TDS were lowest in the SFM section, indicating that the riparian porous aquifer was essential in regulating river hydrochemistry, thus reducing its spatiotemporal variations in the alpine area. In the mountain glacier-hillslope-riparian porous aquifer-river system, the river was mainly recharged by groundwater with insufficient water-rock interactions due to the rapid flow owing to the high elevation difference and high permeability of the riparian quaternary porous aquifers. Our findings provide insights into the construction of hydrogeochemical models in alpine areas and are practically important for the scientific management of water resources in the Qinghai-Tibet Plateau.