Atom transfer radical polymerization of styrene under pulsed microwave irradiation

被引：54
|
作者：
Cheng, ZP [1 ]
Zhu, XL [1 ]
Zhou, NC [1 ]
Zhu, J [1 ]
Zhang, ZB [1 ]
机构：
[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China
来源：
RADIATION PHYSICS AND CHEMISTRY | 2005年 / 72卷 / 06期
关键词：
pulsed microwave irradiation; atom transfer radical polymerization; reverse atom transfer radical polymerization; styrene; living polymerization;
D O I：
10.1016/j.radphyschem.2004.04.134
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A homogeneous solution atom transfer radical polymerization (ATRP) and reverse atom transfer radical polymerization (RATRP) of styrene (St) in N,N-dimethylformamide (DMF) were successfully carried out under pulsed microwave irradiation (PMI), using 1-bromo-1-phenylethane (1-PEBr)/CuCl/N,N,N',N'',N"-pentamethyldiethy-lenetriamine (PMDETA) as an initiating system at 85degreesC and 2,2'-azo-bis-isobutyrontrile (AIBN)/CUCl2/PMDETA as an initiating system at 95degreesC, respectively. The polymerization rates under PMI were greatly increased in comparison with those under identical conventional heating (CH). (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：695 / 701
页数：7
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