Atom transfer radical polymerization of styrene under pulsed microwave irradiation

被引：54
|
作者：
Cheng, ZP [1 ]
Zhu, XL [1 ]
Zhou, NC [1 ]
Zhu, J [1 ]
Zhang, ZB [1 ]
机构：
[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China
来源：
RADIATION PHYSICS AND CHEMISTRY | 2005年 / 72卷 / 06期
关键词：
pulsed microwave irradiation; atom transfer radical polymerization; reverse atom transfer radical polymerization; styrene; living polymerization;
D O I：
10.1016/j.radphyschem.2004.04.134
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A homogeneous solution atom transfer radical polymerization (ATRP) and reverse atom transfer radical polymerization (RATRP) of styrene (St) in N,N-dimethylformamide (DMF) were successfully carried out under pulsed microwave irradiation (PMI), using 1-bromo-1-phenylethane (1-PEBr)/CuCl/N,N,N',N'',N"-pentamethyldiethy-lenetriamine (PMDETA) as an initiating system at 85degreesC and 2,2'-azo-bis-isobutyrontrile (AIBN)/CUCl2/PMDETA as an initiating system at 95degreesC, respectively. The polymerization rates under PMI were greatly increased in comparison with those under identical conventional heating (CH). (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：695 / 701
页数：7
相关论文
共 50 条
  • [31] Synthesis of poly (propylene glycol-g-styrene) from atom transfer radical polymerization
    Huang, CG
    Wan, XL
    Ying, SK
    ACTA POLYMERICA SINICA, 2000, (04) : 467 - 471
  • [32] Emulsion copolymerization of styrene and butyl acrylate by reverse atom transfer radical polymerization
    Wu, Yumin
    Dong, Guoliang
    Xu, Jun
    Ni, Guangdi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 126 (03) : 1152 - 1158
  • [33] Rate-accelerating of Boric Oxide for Atom Transfer Radical Polymerization of Styrene
    Lin Rui
    Zhuang Jia-Ming
    Xu Rui
    Zhao Jun
    Lin Hua-Duan
    Zou You-Si
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2008, 29 (11): : 2299 - 2302
  • [34] Effects of dual initiators and catalytic additives on atom transfer radical polymerization of styrene
    Hyung Jin Oh
    Young-Kwon Park
    Young Soo Ko
    Research on Chemical Intermediates, 2011, 37 : 1257 - 1265
  • [35] Reverse atom transfer radical polymerization of styrene with copper-based catalyst
    Qin, DQ
    Qin, SH
    Qiu, KY
    CHINESE JOURNAL OF POLYMER SCIENCE, 2001, 19 (01): : 59 - 64
  • [36] Atom transfer radical polymerization of styrene using multifunctional iniferter reagents as initiators
    Zhang, Wei
    Wang, Chengchao
    Li, Daoguang
    Song, Qing
    Cheng, Zhenping
    Zhu, Xiulin
    MACROMOLECULAR SYMPOSIA, 2008, 261 : 23 - 31
  • [37] Radical copolymerization of N-subsituted maleimides with styrene using atom transfer radical polymerization
    Chen, GQ
    Wu, ZQ
    Wu, JR
    Li, ZC
    Sun, XM
    Li, FM
    ACTA POLYMERICA SINICA, 1999, (04) : 506 - 508
  • [38] L-menthol-based initiators for atom transfer radical polymerization of styrene
    Vishwakarma, Sambhav
    Kumari, Archana
    Mitra, Kheyanath
    Singh, Shikha
    Singh, Rajshree
    Singh, Jaydeep
    Gupta, Susanta K. Sen
    Ray, Biswajit
    JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (38)
  • [39] Effects of dual initiators and catalytic additives on atom transfer radical polymerization of styrene
    Oh, Hyung Jin
    Park, Young-Kwon
    Ko, Young Soo
    RESEARCH ON CHEMICAL INTERMEDIATES, 2011, 37 (09) : 1257 - 1265
  • [40] Reverse atom transfer radical polymerization of acrylonitrile
    Hou, C
    Qu, R
    Ying, L
    Wang, CG
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 99 (01) : 32 - 36
12345