Designs and applications of multi-functional covalent organic frameworks in rechargeable batteries

被引：71
作者：
An, Yongkang [1 ]
Tan, Shuangshuang [1 ]
Liu, Yu [1 ]
Zhu, Kai [2 ]
Hu, Lei [3 ]
Rong, Yaoguang [4 ]
An, Qinyou [1 ,5 ]
机构：
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
[2] Nanjing Univ, Sch Informat Sci & Engn, Jinling Coll, Nanjing 210089, Jiangsu, Peoples R China
[3] Xi An Jiao Tong Univ, Key Lab Thermofluid Sci & Engn, Xian 710049, Shaanxi, Peoples R China
[4] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Hubei, Peoples R China
[5] Guangdong Lab Xianhu Hydrogen Valley, Foshan Xianhu Lab Adv Energy Sci & Technol, Foshan 528200, Guangdong, Peoples R China
来源：
ENERGY STORAGE MATERIALS | 2021年 / 41卷
基金：
中国国家自然科学基金;
关键词：
Covalent organic frameworks; Li-ion batteries; Sodium-ion batteries; Li-S batteries; Solid-state electrolytes; ELECTRODE MATERIALS; CATHODE MATERIALS; HIGH-ENERGY; CONJUGATED POLYMERS; ANODE MATERIAL; EFFICIENT CATHODE; CARBON NANOTUBES; CHARGE STORAGE; AZO-COMPOUNDS; BAND-GAP;
D O I：
10.1016/j.ensm.2021.06.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Recently, covalent organic frameworks (COFs) have attracted widespread attention for the research in rechargeable batteries due to their inerratic porous structure, adjustable porosity and designable framework. The porous structure with adjustable pore size is stacked into a one-dimensional ordered channel through the n n interaction, which provides favorable pathways for rapid charge transport. Terrific structural designability exhibits unique advantages in electrochemical energy storage systems (EESS), such as active site diversity, structural stability, lithium and sulfur affinity, which furnishes a novel perspective for settling various problems of rechargeable batteries. This review introduces the structural features and reaction mechanisms of COF materials, then summarizes the design concepts and latest applications of redox-active (cathode and anode materials) and non-redox active (separators, hosts and solid-state electrolytes) COFs in rechargeable batteries. Finally, challenges and perspectives in these fields are discussed.
引用
收藏
页码：354 / 379
页数：26
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