Fluorescence and Sensing Applications of Graphene Oxide and Graphene Quantum Dots: A Review

被引:287
作者
Zheng, Peng [1 ]
Wu, Nianqiang [1 ]
机构
[1] West Virginia Univ, Dept Mech & Aerosp Engn, POB 6106, Morgantown, WV 26506 USA
基金
美国国家科学基金会; 美国国家卫生研究院;
关键词
biosensors; fluorescence; graphene; quantum dots; sensors; WAVELENGTH-DEPENDENT FLUORESCENCE; RESONANCE ENERGY-TRANSFER; TARGETED DRUG-DELIVERY; LOGIC GATE; CONJUGATED GRAPHENE; PATHOGEN DETECTION; LIVING CELLS; TUMOR-CELLS; PLATFORM; DNA;
D O I
10.1002/asia.201700814
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene oxide and graphene quantum dots are attractive fluorophores that are inexpensive, nontoxic, photostable, water-soluble, biocompatible, and environmentally friendly. They find extensive applications in fluorescent biosensors and chemosensors, in which they serve as either fluorophores or quenchers. As fluorophores, they display tunable photoluminescence emission and the giant red-edge effect. As quenchers, they exhibit a remarkable quenching efficiency through either electron transfer or Forster resonance energy transfer (FRET) process. In this review, the origin of fluorescence and the mechanism of excitation wavelength-dependent fluorescence of graphene oxide and graphene quantum dots are discussed. Sensor design strategies based on graphene oxide and graphene quantum dots are presented. The applications of these sensors in health care, the environment, agriculture, and food safety are highlighted.
引用
收藏
页码:2343 / 2353
页数:11
相关论文
共 82 条
[31]   A Graphene Oxide Based Immuno-biosensor for Pathogen Detection [J].
Jung, Jae Hwan ;
Cheon, Doo Sung ;
Liu, Fei ;
Lee, Kang Bum ;
Seo, Tae Seok .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (33) :5708-5711
[32]   Highly Fluorescent Graphene Oxide-Poly(vinyl alcohol) Hybrid: An Effective Material for Specific Au3+ Ion Sensors [J].
Kundu, Aniruddha ;
Layek, Rama K. ;
Kuila, Atanu ;
Nandi, Arun K. .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (10) :5576-5582
[33]   Label free selective detection of estriol using graphene oxide-based fluorescence sensor [J].
Kushwaha, H. S. ;
Sao, Reshma ;
Vaish, Rahul .
JOURNAL OF APPLIED PHYSICS, 2014, 116 (03)
[34]   Luminescent Graphene Oxide with a Peptide-Quencher Complex for Optical Detection of Cell-Secreted Proteases by a Turn-On Response [J].
Kwak, Seon-Yeong ;
Yang, Jin-Kyoung ;
Jeon, Su-Ji ;
Kim, Hye-In ;
Yim, Joonhyuk ;
Kang, Homan ;
Kyeong, San ;
Lee, Yoon-Sik ;
Kim, Jong-Ho .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (32) :5119-5128
[35]  
Lakowicz J. R., 2006, Principles of fluorescence spectroscopy, DOI [DOI 10.1007/978-0-387-46312-4, DOI 10.1007/978-0-387-46312-4/COVER]
[36]   Graphene Oxide Nanoparticles as a Nonbleaching Optical Probe for Two-Photon Luminescence Imaging and Cell Therapy [J].
Li, Jing-Liang ;
Bao, Hong-Chun ;
Hou, Xue-Liang ;
Sun, Lu ;
Wang, Xun-Gai ;
Gu, Min .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1830-1834
[37]   Detection of lead (II) with a "turn-on" fluorescent biosensor based on energy transfer from CdSe/ZnS quantum dots to graphene oxide [J].
Li, Ming ;
Zhou, Xuejiao ;
Guo, Shouwu ;
Wu, Nianqiang .
BIOSENSORS & BIOELECTRONICS, 2013, 43 :69-74
[38]   Fluorescent aptamer-functionalized graphene oxide biosensor for label-free detection of mercury(II) [J].
Li, Ming ;
Zhou, Xuejiao ;
Ding, Weiqiang ;
Guo, Shouwu ;
Wu, Nianqiang .
BIOSENSORS & BIOELECTRONICS, 2013, 41 :889-893
[39]   Fingerprinting photoluminescence of functional groups in graphene oxide [J].
Li, Ming ;
Cushing, Scott K. ;
Zhou, Xuejiao ;
Guo, Shouwu ;
Wu, Nianqiang .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (44) :23374-23379
[40]   Sensitive and Rapid Screening of T4 Polynucleotide Kinase Activity and Inhibition Based on Coupled Exonuclease Reaction and Graphene Oxide Platform [J].
Lin, Lei ;
Liu, Yang ;
Zhao, Xin ;
Li, Jinghong .
ANALYTICAL CHEMISTRY, 2011, 83 (22) :8396-8402