Effect of Sodium Pyrophosphate on the Reverse Flotation of Dolomite from Apatite

被引:53
作者
Chen, Yanfei [1 ]
Feng, Qiming [1 ]
Zhang, Guofan [1 ]
Liu, Dezhi [1 ]
Liu, Runzhe [1 ]
机构
[1] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Hunan, Peoples R China
关键词
sodium pyrophosphate; flotation; depression; apatite; dolomite; PHOSPHATE ORES; COLLOPHANITE ORE; COLLECTOR; ACID; PERFORMANCE; DEPRESSANT; CARBONATES; SCHEELITE; MECHANISM; MINERALS;
D O I
10.3390/min8070278
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
In this study, the effect of sodium pyrophosphate (NaPP) on the separation of apatite from dolomite by flotation was systematically investigated. Flotation results revealed that NaPP could selectively depress the flotation of apatite, thus realizing the separation of apatite from dolomite. Further, the selective depression mechanism of NaPP was studied through zeta potential measurements, contact anglemeasurements, and X-ray photoelectron spectroscopy (XPS) analysis. The results demonstrated that the adsorption of sodiumoleate (NaOL) onto apatite surface was depressed by the preferential interaction of NaPP with active Ca sites. For dolomite, while the presence of NaPP hindered the interaction of NaOL with active Ca sites, it appeared to enhance the reactivity with active Mg sites. Thus, the adsorption of NaOL onto dolomite surface was hardly influenced. In this way, the separation of apatite from dolomite was achieved.
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页数:11
相关论文
共 25 条
[1]   Evaluation of flotation strategies for sedimentary phosphates with siliceous and carbonates gangues [J].
Abdel-Khalek, NA .
MINERALS ENGINEERING, 2000, 13 (07) :789-793
[2]   EFFECTS OF DISSOLVED MINERAL SPECIES ON THE ELECTROKINETIC BEHAVIOR OF CALCITE AND APATITE [J].
AMANKONAH, JO ;
SOMASUNDARAN, P .
COLLOIDS AND SURFACES, 1985, 15 (3-4) :335-353
[3]   A mixed collector system for phosphate flotation [J].
Cao, Qinbo ;
Cheng, Jinhua ;
Wen, Shuming ;
Li, Chengxiu ;
Bai, Shaojun ;
Liu, Dan .
MINERALS ENGINEERING, 2015, 78 :114-121
[4]   The flotation separation of scheelite from calcite and fluorite using dextran sulfate sodium as depressant [J].
Chen, Wei ;
Feng, Qiming ;
Zhang, Guofan ;
Yang, Qun ;
Zhang, Cheng ;
Xu, Fengping .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2017, 169 :53-59
[5]   Effect of ionic species on the performance of apatite flotation [J].
dos Santos, Mariana A. ;
Santana, Ricardo C. ;
Capponi, Fabiano ;
Ataide, Carlos H. ;
Barrozo, Marcos A. S. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2010, 76 (01) :15-20
[6]   THE EFFECT OF SLIME COATINGS OF THE SERPENTINE MINERALS, CHRYSOTILE AND LIZARDITE, ON PENTLANDITE FLOTATION [J].
EDWARDS, CR ;
KIPKIE, WB ;
AGAR, GE .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 1980, 7 (01) :33-42
[7]   FLOTATION OF CARBONATES FROM PHOSPHATE ORES IN ACIDIC MEDIA [J].
ELGILLANI, DA ;
ABOUZEID, AZM .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 1993, 38 (3-4) :235-256
[8]   A review of the beneficiation of calcareous phosphate ores using organic acid leaching [J].
Gharabaghi, Mahdi ;
Irannajad, Mehdi ;
Noaparast, Mohammad .
HYDROMETALLURGY, 2010, 103 (1-4) :96-107
[9]   Reagents in igneous phosphate ores flotation [J].
Guimaraes, RC ;
Araujo, AC ;
Peres, AEC .
MINERALS ENGINEERING, 2005, 18 (02) :199-204
[10]   Investigation of Langmuir monofilms and flotation experiments with anionic/cationic collector mixtures [J].
Helbig, C ;
Baldauf, H ;
Mahnke, J ;
Stöckelhuber, KW ;
Schulze, HJ .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 1998, 53 (03) :135-144