Triboluminescence of Lanthanide Coordination Polymers with Face-to-Face Arranged Substituents

被引:66
作者
Hirai, Yuichi [1 ]
Nakanishi, Takayuki [2 ]
Kitagawa, Yuichi [2 ]
Fushimi, Koji [2 ]
Seki, Tomohiro [2 ]
Ito, Hajime [2 ]
Hasegawa, Yasuchika [2 ]
机构
[1] Hokkaido Univ, Grad Sch Chem Sci & Engn, Kita 13 Jo,Nishi 8 Chome, Sapporo, Hokkaido 0608628, Japan
[2] Hokkaido Univ, Fac Engn, Kita 13 Jo,Nishi 8 Chome, Sapporo, Hokkaido 0608628, Japan
关键词
coordination polymers; europium; photoluminescence; terbium; triboluminescence; CRYSTAL-STRUCTURES; COMPLEXES; LUMINESCENCE; SENSOR; TRIETHYLAMMONIUM; TB(III); EU(III); METAL; OXIDE;
D O I
10.1002/anie.201703638
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Luminescence upon the grinding of solid materials (triboluminescence, TL) has long been a puzzling phenomenon in natural science and has also attracted attention because of its broad application in optics. It has been generally considered that the TL spectra exhibit similar profiles as those of photoluminescence (PL), although they occur from distinct stimuli. Herein, we describe for the first time a large spectral difference between these two physical phenomena using lanthanide(III) coordination polymers with efficient TL and PL properties. They are composed of emission centers (Tb-III and Eu-III ions), antenna (hexafluoroacetylacetonate=hfa), and bridging ligands (2,5-bis(diphenylphosphoryl)furan=dpf). The emission color upon grinding (yellow TL) is clearly different from that upon UV irradiation (reddish-orange PL) in Tb-III/Eu-III-mixed coordination polymers [Tb,Eu(hfa)(3)(dpf)](n) (Tb/Eu=1). The results directly indicate the discrete excitation processes of PL and TL.
引用
收藏
页码:7171 / 7175
页数:5
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