From Lead Halide Perovskites to Lead-Free Metal Halide Perovskites and Perovskite Derivatives

被引:794
作者
Xiao, Zewen [1 ]
Song, Zhaoning [2 ,3 ]
Yan, Yanfa [2 ,3 ]
机构
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Hubei, Peoples R China
[2] Univ Toledo, Dept Phys & Astron, Toledo, OH 43607 USA
[3] Univ Toledo, Wright Ctr Photovolta Innovat & Commercializat, Toledo, OH 43607 USA
关键词
double perovskites; halide perovskites; lead-free; optoelectronic properties; solar cells; DENSITY-FUNCTIONAL THEORY; LIFE-CYCLE ASSESSMENT; SOLAR-CELLS; IODIDE PEROVSKITE; PHOTOVOLTAIC PERFORMANCE; OPTICAL-PROPERTIES; THIN-FILMS; INTRINSIC DEFECTS; EFFECTIVE MASSES; CHARGE-CARRIERS;
D O I
10.1002/adma.201803792
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Despite the exciting progress on power conversion efficiencies, the commercialization of the emerging lead (Pb) halide perovskite solar cell technology still faces significant challenges, one of which is the inclusion of toxic Pb. Searching for Pb-free perovskite solar cell absorbers is currently an attractive research direction. The approaches used for and the consequences of Pb replacement are reviewed herein. Reviews on the theoretical understanding of the electronic, optical, and defect properties of Pb and Pb-free halide perovskites and perovskite derivatives are provided, as well as the experimental results available in the literature. The theoretical understanding explains well why Pb halide perovskites exhibit superior photovoltaic properties, but Pb-free perovskites and perovskite derivatives do not.
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页数:22
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