Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues

被引：103
作者：
Tang, Christina Y. [1 ]
Thompson, Amber L. [1 ]
Aldridge, Simon [1 ]
机构：
[1] Univ Oxford, Oxford OX1 3QR, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
alkenes; aminoboranes; dehydrogenation; iridium; rhodium; AMMONIA BORANE DEHYDROGENATION; METAL-CATALYZED REACTIONS; AMINE-BORANE; H ACTIVATION; AMIDOBORANE COMPLEXES; RUTHENIUM COMPLEX; HYDROGEN STORAGE; BORYL LIGANDS; BORON; REACTIVITY;
D O I：
10.1002/anie.200906171
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2N= BH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands-in contrast to isoelectronic alkene donors-bind in an end-on fashion through a bis(o-borane) binding motif (see structure). (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：921 / 925
页数：5
相关论文
共 65 条
[41]   Dehydrocoupling Reactions of Borane-Secondary and -Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines [J].
Kawano, Yasuro ;
Uruichi, Mikio ;
Shimoi, Mamoru ;
Taki, Seitaro ;
Kawaguchi, Takayuki ;
Kakizawa, Taeko ;
Ogino, Hiroshi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (41) :14946-14957
[42]   Transition metal boryl complexes [J].
Kays, Deborah L. ;
Aldridge, Simon .
CONTEMPORARY METAL BORON CHEMISTRY I: BORYLENES, BORYLS, BORANE (SIGMA)-COMPLEXES, AND BOROHYDRIDES, 2008, 130 :29-+
[43]  
Liu Z., 2008, Angew. Chem, V120, P248
[44]   B-N versus C-C: How similar are they? [J].
Liu, Zhiqiang ;
Marder, Todd B. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :242-244
[45]   Transition metal catalysed diboration [J].
Marder, TB ;
Norman, NC .
TOPICS IN CATALYSIS, 1998, 5 (1-4) :63-73
[46]   Will we soon be fueling our automobiles with ammonia-borane? [J].
Marder, Todd B. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) :8116-8118
[47]  
Marder ToddB., 2007, Angewandte Chemie, V119, P8262
[48]   Metal-Catalyzed Reactions of Organoboronic Acids and Esters [J].
Miyaura, Norio .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2008, 81 (12) :1535-1553
[49]   Lithium aminoborohydrides. 16. Synthesis and reactions of monomeric and dimeric aminoboranes [J].
Pasumansky, Lubov ;
Haddenham, Dustin ;
Clary, Jacob W. ;
Fisher, Gary B. ;
Goralski, Christian T. ;
Singaram, Bakthan .
JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (05) :1898-1905
[50]   Investigation of the synthesis of {Mo(η5-C5H5)(CO)3}+ fragments partnered with the monoanionic carboranes [closo-CB11H11Br]-, [closo-CB11H6Br6]- and [closo-HCB11Me11]- by silver salt metathesis and hydride abstraction [J].
Patmore, NJ ;
Ingleson, MJ ;
Mahon, MF ;
Weller, AS .
DALTON TRANSACTIONS, 2003, (14) :2894-2904
1234567