Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues

被引：103

作者：

Tang, Christina Y. ^{[1
]}

Thompson, Amber L. ^{[1
]}

Aldridge, Simon ^{[1
]}

机构：

[1] Univ Oxford, Oxford OX1 3QR, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

alkenes; aminoboranes; dehydrogenation; iridium; rhodium; AMMONIA BORANE DEHYDROGENATION; METAL-CATALYZED REACTIONS; AMINE-BORANE; H ACTIVATION; AMIDOBORANE COMPLEXES; RUTHENIUM COMPLEX; HYDROGEN STORAGE; BORYL LIGANDS; BORON; REACTIVITY;

D O I：

10.1002/anie.200906171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2N= BH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands-in contrast to isoelectronic alkene donors-bind in an end-on fashion through a bis(o-borane) binding motif (see structure). (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：921 / 925

页数：5

相关论文

共 65 条

[31] Microwave-Accelerated Iridium-Catalyzed Borylation of Aromatic C-H Bonds [J].

Harrisson, Peter ;

Morris, James ;

Marder, Todd B. ;

Steel, Patrick G. .

ORGANIC LETTERS, 2009, 11 (16) :3586-3589

[32]

HARTWIG JF, 2005, HDB C H TRANSFORMATI, V2, P605

[33] σ-borane complexes of iridium:: Synthesis and structural characterization [J].

Hebden, Travis J. ;

Denney, Melanie C. ;

Pons, Vincent ;

Piccoli, Paula M. B. ;

Koetzle, Thomas F. ;

Schultz, Arthur J. ;

Kaminsky, Werner ;

Goldberg, Karen I. ;

Heinekey, D. Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10812-10820

[34] Synthesis and characterization of a cationic ruthenium complex featuring an unusual bis(η2-BH) monoborane ligand [J].

Hesp, Kevin D. ;

Rankin, Matthew A. ;

McDonald, Robert ;

Stradiotto, Mark .

INORGANIC CHEMISTRY, 2008, 47 (17) :7471-7473

[35] Intramolecular C-H activation involving a rhodium-imidazol-2-ylidene complex and its reaction with H2 and CO [J].

Huang, JK ;

Stevens, ED ;

Nolan, SP .

ORGANOMETALLICS, 2000, 19 (06) :1194-1197

[36] Transition metal-boryl compounds: Synthesis, reactivity, and structure [J].

Irvine, GJ ;

Lesley, MJG ;

Marder, TB ;

Norman, NC ;

Rice, CR ;

Robins, EG ;

Roper, WR ;

Whittell, GR ;

Wright, LJ .

CHEMICAL REVIEWS, 1998, 98 (08) :2685-2722

[37] Metal-catalyzed reactions of diborons for synthesis of organoboron compounds [J].

Ishiyama, T ;

Miyaura, N .

CHEMICAL RECORD, 2004, 3 (05) :271-280

[38]

Ishiyama T., 2005, HDB C H TRANSFORMATI, V1, P126

[39] Heterogeneous or homogeneous catalysis? Mechanistic studies of the rhodium-catalyzed dehydrocoupling of amine-borane and phosphine-borane adducts [J].

Jaska, CA ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) :9776-9785

[40] Transition metal-catalyzed formation of boron-nitrogen bonds: Catalytic dehydrocoupling of amine-borane adducts to form aminoboranes and borazines [J].

Jaska, CA ;

Temple, K ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9424-9434

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