Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues

被引:103
作者
Tang, Christina Y. [1 ]
Thompson, Amber L. [1 ]
Aldridge, Simon [1 ]
机构
[1] Univ Oxford, Oxford OX1 3QR, England
基金
英国工程与自然科学研究理事会;
关键词
alkenes; aminoboranes; dehydrogenation; iridium; rhodium; AMMONIA BORANE DEHYDROGENATION; METAL-CATALYZED REACTIONS; AMINE-BORANE; H ACTIVATION; AMIDOBORANE COMPLEXES; RUTHENIUM COMPLEX; HYDROGEN STORAGE; BORYL LIGANDS; BORON; REACTIVITY;
D O I
10.1002/anie.200906171
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2N= BH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands-in contrast to isoelectronic alkene donors-bind in an end-on fashion through a bis(o-borane) binding motif (see structure). (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:921 / 925
页数:5
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