Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)zinc(II)

被引：11

作者：

Liu, JW ^{[1
]}

Gao, S ^{[1
]}

Hua, LH ^{[1
]}

Gu, CS ^{[1
]}

Zhao, H ^{[1
]}

Zhao, JG ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804026388

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Zn(H2IDC)(2)(H2O)(2)] (where H2IDC- is the 5-carboxy-1H-imidazole-4-carboxylate monoanion, C5H3N2O4), the Zn-II atom is located on an inversion centre, is trans-coordinated by two N,O-bidentate H2IDC- ligands and two water molecules and shows an approximately octahedral configuration. A three-dimensional supramolecular architecture is formed via hydrogen-bond interactions.

引用

页码：M1697 / M1699

页数：3

共 11 条

[1]

Higashi T., 1995, ABSCOR

[2]

JOHNSON CK, 1976, ORNL5138 ORTEP2

[3] trans-Diaquabis(1H-imidazole-4,5-dicarboxylate-κ2N3,O4)manganese(II) [J].

Ma, CB ;

Chen, F ;

Chen, CN ;

Liu, QT .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (12) :M516-M518

[4] Isolation of the first ferromagnetically coupled Mn(III/IV) complex [J].

Rajendiran, TM ;

Kirk, ML ;

Setyawati, IA ;

Caudle, MT ;

Kampf, JW ;

Pecoraro, VL .

CHEMICAL COMMUNICATIONS, 2003, (07) :824-825

[5]

*RIG CORP, 1998, RAPID AUTO

[6]

*RIG MSC INC, 2002, CRYSTALSTRUCTURE

[7] Oxovanadium(IV) complexes of imidazole-4-acetic, imidazole-4,5-dicarboxylic and pyrazole-3,5-dicarboxylic acids [J].

Sanna, D ;

Micera, G ;

Buglyo, P ;

Kiss, T ;

Gajda, T ;

Surdy, P .

INORGANICA CHIMICA ACTA, 1998, 268 (02) :297-305

[8] Synthesis and characterisation of some ruthenium(II) complexes of α-N heterocyclic carboxylic acids -: X-ray structures of cis-[Ru(PPh3)2(L1)2]•2CH3OH and cis-[Ru(PPh3)2(L3H)2] (L1H = pyridine 2-carboxylic acid and L3H2 = imidazole 4,5-dicarboxylic acid) [J].

Sengupta, P ;

Dinda, R ;

Ghosh, S ;

Sheldrick, WS .

POLYHEDRON, 2001, 20 (28) :3349-3354

[9]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR

[10] Diaquabis(1H-imidazole-4,5-dicarboxylato-κN3)-cobalt(II) N,N-dimethylformamide disolvate [J].

Xiao, HP ;

Li, XH ;

Shi, Q .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M1519-M1521

← 1 2 →