On the surface tension of room temperature ionic liquids

被引：6

作者：

Marcus, Yizhak ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel

来源：

FLUID PHASE EQUILIBRIA | 2017年 / 444卷

关键词：

Room temperature ionic liquid; Surface tension; Ionic volumes; Void space volume and area; Temperature dependence; DENSITY; IMIDAZOLIUM; DEPENDENCE; VISCOSITY; TRANSPORT; PARACHOR; VOLUMES; ANION; FLOW;

D O I：

10.1016/j.fluid.2017.04.017

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Following previous workers, the surface tension of room temperature ionic liquids (RTILs) is shown to depend reciprocally on the surface area of the void space in the RTILs. The void space in liquids in general and in RTILs in particular can be expressed in several manners. The fraction of free space in RTILs can be estimated well and most simply from their actual molar volumes and the ionic volumes of the constituting ions. The temperature dependence of the surface tension is explored and shown to be essentially independent on the natures of the RTILs. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：56 / 60

页数：5

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