Palladium-catalyzed desulfitative cross-coupling of arylsulfinates with arylboronic acids

被引:27
作者
Cheng, Kai [1 ]
Yu, Hai-Zhu [2 ]
Zhao, Baoli [1 ]
Hu, Sai [3 ]
Zhang, Xian-Man [1 ]
Qi, Chenze [1 ]
机构
[1] Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China
[2] Univ Sci & Technol Beijing, Dept Polymer Sci & Engn, Beijing 100083, Peoples R China
[3] Ningbo Univ, Coll Mat Sci & Chem Engn, Ningbo 310014, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
SUZUKI-MIYAURA REACTION; ARYL SULFINIC ACIDS; DIRECT ESI-MS; ARENESULFONYL CHLORIDES; BOND FORMATION; DECARBOXYLATIVE PALLADATION; ARYLSULFONYL CHLORIDES; SULFONYL CHLORIDES; ALKENYL PHOSPHATES; CARBOXYLIC-ACIDS;
D O I
10.1039/c4ra07455f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium (Pd)-catalyzed desulfitative cross-coupling reactions of sodium arylsulfinates with a wide variety of arylboronic acids were achieved in good to excellent yields under simple aerobic conditions. These catalytic reactions could be accelerated by addition of a catalytic amount of Cu(II) salts as co-catalyst. Moreover, these reactions were tolerant to all of the tested functional groups, making them attractive alternatives to the traditional cross-coupling reactions.
引用
收藏
页码:57923 / 57928
页数:6
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