Linear isotherm for compressed molten alkali metals

被引:18
作者
Ghatee, MH [1 ]
Mousazadeh, MH [1 ]
Boushehri, A [1 ]
机构
[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran
关键词
alkali metals; density; equation of state; linear regularity;
D O I
10.1023/A:1021423824201
中图分类号
O414.1 [热力学];
学科分类号
摘要
Molten alkali metals are shown to be in the domain of the newly developed linear regularity that is valid for pure compressed liquids and liquid mixtures. It holds in the range of melting to boiling temperature and shows deviations as the critical temperature is approached. The agreement with experimental data is better than 1.4% when it is used to predict the density of molten Li, Na, K, Rb; and Cs metals. A reasonable conformity with the ISM statistical mechanical equation of stale is manifested.
引用
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页码:317 / 330
页数:14
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