Structures of bis(fluorosulfonyl)imide HN(SO2F)2, bis(trifluoromethylsulfonyl)imide HN(SO2CF3)2, and their potassium salts at 150 K

被引：51
|
作者：
Zak, Z
Ruzicka, A
Michot, C
机构：
[1] Masaryk Univ, Dept Inorgan Chem, CS-61137 Brno, Czech Republic
[2] Ecole Natl Super Electrochim & Electrome Grenoble, Lab Ion & Electrochim Solides, F-38402 St Martin Dheres, France
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1998年 / 213卷 / 04期
关键词：
D O I：
10.1524/zkri.1998.213.4.217
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structures of HN(SO2R)(2), R=E CF3 are formed by molecules linked by hydrogen bonds to infinite chains. While KN(SO2F)(2) is composed of alternating cations and anions, HN(SO2CF3)(2) exhibits a pronounced layer structure. In the acids, the substituents -R are in trans configuration being on the opposite sides of the plane defined by S-N-S bonds but in the salts the cis configuration with both substituents on the same side of the S-N-S plane is preferred, probably due to numerous metal-anion interactions.
引用
收藏
页码：217 / 222
页数：6
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