Reactions of Negative Ions with ClN3 at 300 K

被引:1
|
作者
Eyet, Nicole [1 ,2 ,3 ]
Freel, Keith [1 ,4 ]
Heaven, Michael C. [4 ]
Viggiano, A. A. [1 ]
机构
[1] USAF, Res Lab, Space Vehicles Directorate, Hanscom AFB, MA 01731 USA
[2] St Anselm Coll, Dept Chem, Manchester, NH 03102 USA
[3] Boston Coll, Inst Sci Res, Chestnut Hill, MA 02167 USA
[4] Emory Univ, Dept Chem, Atlanta, GA 30322 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY A | 2010年 / 114卷 / 25期
关键词
CHLORINE AZIDE; ENERGY; MOLECULES; FORMULA; LASER;
D O I
10.1021/jp102951z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reactivity of ClN3 with 17 negative ions has been investigated at 300 K. The electron affinity (EA) of ClN3 was bracketed to be between that of NO2 and N-3, giving EA(ClN3) = 2.48 +/- 0.20 eV, in agreement with an electronic structure calculation. Reaction rate constants and product ion branching ratios were measured. In nearly all cases the major product of the reaction was chloride ions. Charge transfer, N-3(-) production, and 0 atom incorporation is also observed. DFT calculations of stable complexes and transition states are presented for two typical ions. Mechanistic details are discussed in terms of reaction coordinate diagrams.
引用
收藏
页码:6832 / 6836
页数:5
相关论文
共 50 条
  • [21] Timing of cognitive decline in CLN3 disease
    Kuper, Willemijn F. E.
    van Alfen, Claudia
    Rigterink, Roeliene H.
    Fuchs, Sabine A.
    van Genderen, Maria M.
    van Hasselt, Peter M.
    JOURNAL OF INHERITED METABOLIC DISEASE, 2018, 41 (02) : 257 - 261
  • [22] Studies of membrane association of CLN3 protein
    Kaczmarski, W
    Wisniewski, KE
    Golabek, A
    Kaczmarski, A
    Kida, E
    Michalewski, M
    MOLECULAR GENETICS AND METABOLISM, 1999, 66 (04) : 261 - 264
  • [23] Photodissociation dynamics of ClN3 at 193 nm
    Goncher, Scott J.
    Sveum, Niels E.
    Moore, David T.
    Bartlett, Nate D.
    Neumark, Daniel M.
    JOURNAL OF CHEMICAL PHYSICS, 2006, 125 (22):
  • [24] The Batten disease associated protein CLN3 is required for the efflux of lysosomal K+
    Best, Hannah
    Honeybun, Llinos
    Waller-Evans, Helen
    Lloyd-Evans, Emyr
    MOLECULAR GENETICS AND METABOLISM, 2023, 138 (02) : 17 - 17
  • [25] Intracellular trafficking of the JNCL protein CLN3
    Haskell, RE
    Derksen, TA
    Davidson, BL
    MOLECULAR GENETICS AND METABOLISM, 1999, 66 (04) : 253 - 260
  • [26] CLN3 clinches lysosomes in clearance of glycerophospholipids
    Guang Lu
    HanMing Shen
    LifeMetabolism, 2023, 2 (01) : 6 - 7
  • [27] Mitochondrial abnormalities in CLN2 and CLN3 forms of Batten disease
    Dawson, G
    Kilkus, J
    Siakotos, AN
    Singh, I
    MOLECULAR AND CHEMICAL NEUROPATHOLOGY, 1996, 29 (2-3) : 227 - 235
  • [28] CLN5 and CLN3 function as a complex to regulate endolysosome function
    Yasa, Seda
    Sauvageau, Etienne
    Modica, Graziana
    Lefrancois, Stephane
    BIOCHEMICAL JOURNAL, 2021, 478 (12) : 2339 - 2357
  • [29] Repurposing of tamoxifen ameliorates CLN3 and CLN7 disease phenotype
    Soldati, Chiara
    Lopez-Fabuel, Irene
    Wanderlingh, Luca G.
    Garcia-Macia, Marina
    Monfregola, Jlenia
    Esposito, Alessandra
    Napolitano, Gennaro
    Guevara-Ferrer, Marta
    Scotto Rosato, Anna
    Krogsaeter, Einar K.
    Paquet, Dominik
    Grimm, Christian M.
    Montefusco, Sandro
    Braulke, Thomas
    Storch, Stephan
    Mole, Sara E.
    De Matteis, Maria A.
    Ballabio, Andrea
    Sampaio, Julio L.
    McKay, Tristan
    Johannes, Ludger
    Bolanos, Juan P.
    Medina, Diego L.
    EMBO MOLECULAR MEDICINE, 2021, 13 (10)
  • [30] Association between CLN3 (neuronal ceroid lipofuscinosis, CLN3 type) gene expression and clinical characteristics of breast cancer patients
    Makoukji, Joelle
    Raad, Mohamad
    Genadry, Katia
    El-Sitt, Sally
    Makhoul, Nadine J.
    Aldin, Ehab Saad
    Nohra, Eden
    Jabbour, Mark
    Sangaralingam, Ajanthah
    Chelala, Claude
    Habib, Robert H.
    Boulos, Fouad
    Tfayli, Arafat
    Boustany, Rose-Mary
    FRONTIERS IN ONCOLOGY, 2015, 5