Intensification of biodiesel production using dual-frequency counter-current pulsed ultrasound

被引：22

作者：

Yin, Xiulian ^{[1
,2
,3
]}

Zhang, Xuejuan ^{[1
]}

Wan, Miaomiao ^{[1
]}

Duan, Xiuli ^{[1
]}

You, Qinghong ^{[3
,4
,5
]}

Zhang, Jinfeng ^{[1
]}

Li, Songlin ^{[1
]}

机构：

[1] Huaiyin Inst Technol, Sch Life Sci & Food Engn, Huaian 223003, Jiangsu, Peoples R China

[2] Nanjin Forestry Univ, Jiangsu Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Jiangsu, Peoples R China

[3] Huaiyin Inst Technol, Jiangsu Prov Engn Lab Biomass Convers & Proc Inte, Huaian 223003, Peoples R China

[4] Huaiyin Inst Technol, Key Lab Med Exploitat & Utilizat Reg Resources, Huaian 223003, Jiangsu, Peoples R China

[5] Huaiyin Inst Technol, Jiangsu Prov Key Lab Palygorskite Sci & Appl Tech, Huaian 223003, Peoples R China

来源：

ULTRASONICS SONOCHEMISTRY | 2017年 / 37卷

关键词：

Biodiesel; Soybean oil deodorizer distillate; Dual-frequency counter-current pulsed; ultrasound; Kinetic; OIL DEODORIZER DISTILLATE; FATTY-ACID DISTILLATE; ASSISTED SYNTHESIS; CATALYST; TRANSESTERIFICATION; OPTIMIZATION;

D O I：

10.1016/j.ultsonch.2016.12.036

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

Biodiesel production from soybean oil deodorizer distillate intensified by dual-frequency counter-current pulsed ultrasound and the kinetics were studied. Results indicated that the biodiesel conversions enhanced by single-frequency were lower than those enhanced by dual-frequency. For dual-frequency, the biodiesel conversion of SMM was higher than those of SQM. The biodiesel conversion of the combination of 20/28 kHz is the highest. The effects of 20/28 kHz SMM on biodiesel production were studied and optimal conditions were: methanol to triglyceride molar ratio 8:1, catalyst content 1.8%, the water content in feedstock should be less than 0.4%, the acid value of feedstock should be less than 2 mgKOH.g(-1), the biodiesel conversion could reach 96.3%. The kinetics of SMM and SSPU were studied and results showed that the transesterification reaction was pseudo-second order and the energy activation obtained by SMM and SSPU were 18.122 kJ.mol(-1) and 26.034 kJ.mol(-1), respectively. These results showed that transesterification reaction intensified by SMM is easier to take place than SSPU. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：136 / 143

页数：8

共 26 条

[1] Potential alternatives to edible oils for biodiesel production - A review of current work [J].

Balat, Mustafa .

ENERGY CONVERSION AND MANAGEMENT, 2011, 52 (02) :1479-1492

[2] Biodiesel production from non-edible plant oils [J].

Bankovic-Ilic, Ivana B. ;

Starnenkovic, Olivera S. ;

Veljkovic, Vlada B. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (06) :3621-3647

[3] Ultrasonic biodiesel synthesis from crude Jatropha curcas oil with heterogeneous base catalyst: Mechanistic insight and statistical optimization [J].

Choudhury, Hanif A. ;

Goswami, Partha Pratim ;

Malani, Ritesh S. ;

Moholkar, Vijayanand S. .

ULTRASONICS SONOCHEMISTRY, 2014, 21 (03) :1050-1064

[4] Ultrasound-Assisted Synthesis of Biodiesel from Palm Fatty Acid Distillate [J].

Deshmane, Vishwanath G. ;

Gogate, Parag R. ;

Pandit, Aniruddha B. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (17) :7923-7927

[5] Ultrasound assisted synthesis of isopropyl esters from palm fatty acid distillate [J].

Deshmane, Vishwanath G. ;

Gogate, Parag R. ;

Pandit, Aniruddha B. .

ULTRASONICS SONOCHEMISTRY, 2009, 16 (03) :345-350

[6] A review on intensification of synthesis of biodiesel from sustainable feed stock using sonochemical reactors [J].

Gole, Vitthal L. ;

Gogate, Parag R. .

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2012, 53 :1-9

[7] MnO and TiO solid catalysts with low-grade feedstocks for biodiesel production [J].

Gombotz, Kevin ;

Parette, Robert ;

Austic, Greg ;

Kannan, Dheeban ;

Matson, Jack V. .

FUEL, 2012, 92 (01) :9-15

[8] Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock [J].

Gui, M. M. ;

Lee, K. T. ;

Bhatia, S. .

ENERGY, 2008, 33 (11) :1646-1653

[9] Phase diagrams for dual frequency sonic processors using organic liquid medium [J].

Khanna, Swati ;

Chakma, Sankar ;

Moholkar, Vijayanand Suryakant .

CHEMICAL ENGINEERING SCIENCE, 2013, 100 :137-144

[10] Ultrasound assisted biodiesel production in presence of dolomite catalyst [J].

Korkut, Ibrahim ;

Bayramoglu, Mahmut .

FUEL, 2016, 180 :624-629

← 1 2 3 →