Advanced Nanoscale Characterization of Cement Based Materials Using X-Ray Synchrotron Radiation: A Review

被引：39

作者：

Chae, Sejung R. ^{[1
]}

Moon, Juhyuk ^{[1
]}

Yoon, Seyoon ^{[1
]}

Bae, Sungchul ^{[1
]}

Levitz, Pierre ^{[2
]}

Winarski, Robert ^{[3
]}

Monteiro, Paulo J. M. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA

[2] Univ Paris 05, CNRS, Lab PECSA, F-75252 Paris, France

[3] Argonne Natl Lab, Ctr Nanaoscale Mat, Argonne, IL 60439 USA

来源：

INTERNATIONAL JOURNAL OF CONCRETE STRUCTURES AND MATERIALS | 2013年 / 7卷 / 02期

关键词：

X-ray; microscopy; tomography; STXM; X-ray diffraction; high pressure; tobermorite; CSH; fly ash; HIGH-PRESSURE; MAS NMR; MICRODIFFRACTION; ORIENTATION; MICROSCOPE; ALUMINATE; HYDRATION; BEAMLINE; CONCRETE; CRYSTAL;

D O I：

10.1007/s40069-013-0036-1

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

We report various synchrotron radiation laboratory based techniques used to characterize cement based materials in nanometer scale. High resolution X-ray transmission imaging combined with a rotational axis allows for rendering of samples in three dimensions revealing volumetric details. Scanning transmission X-ray microscope combines high spatial resolution imaging with high spectral resolution of the incident beam to reveal X-ray absorption near edge structure variations in the material nanostructure. Microdiffraction scans the surface of a sample to map its high order reflection or crystallographic variations with a micron-sized incident beam. High pressure X-ray diffraction measures compressibility of pure phase materials. Unique results of studies using the above tools are discussed-a study of pores, connectivity, and morphology of a 2,000 year old concrete using nanotomography; detection of localized and varying silicate chain depolymerization in Al-substituted tobermorite, and quantification of monosulfate distribution in tricalcium aluminate hydration using scanning transmission X-ray microscopy; detection and mapping of hydration products in high volume fly ash paste using microdiffraction; and determination of mechanical properties of various AFm phases using high pressure X-ray diffraction.

引用

页码：95 / 110

页数：16

共 55 条

[1]

Attwood D.T., 2000, SOFT XRAYS EXTREME U

[2]

Bentz DP, 1997, J AM CERAM SOC, V80, P3

[3] Review of third and next generation synchrotron light sources [J].

Bilderback, DH ;

Elleaume, P ;

Weckert, E .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2005, 38 (09) :S773-S797

[4] FINITE STRAIN ISOTHERM AND VELOCITIES FOR SINGLE-CRYSTAL AND POLYCRYSTALLINE NACL AT HIGH-PRESSURES AND 300-DEGREE-K [J].

BIRCH, F .

JOURNAL OF GEOPHYSICAL RESEARCH, 1978, 83 (NB3) :1257-1268

[5] Morphological quantification of hierarchical geomaterials by X-ray nano-CT bridges the gap from nano to micro length scales [J].

Brisard, Sebastien ;

Chae, Rosie S. ;

Bihannic, Isabelle ;

Michot, Laurent ;

Guttmann, Peter ;

Thieme, Juergen ;

Schneider, Gerd ;

Monteiro, Paulo J. M. ;

Levitz, Pierre .

AMERICAN MINERALOGIST, 2012, 97 (2-3) :480-483

[6] User facilities around the world [J].

Brown, GE ;

Sutton, SR ;

Calas, G .

ELEMENTS, 2006, 2 (01) :9-14

[7] High spatial resolution X-ray microdiffraction applied to biomaterial studies and archeometry [J].

Cedola, A ;

Lagomarsino, S ;

Komlev, V ;

Rustichelli, F ;

Mastrogiacomo, M ;

Cancedda, R ;

Milita, S ;

Burghammer, M .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2004, 59 (10-11) :1557-1564

[8] Plastic and elastic strains in short and long cracks in Alloy 600 studied by polychromatic X-ray microdiffraction and electron backscatter diffraction [J].

Chao, Jing ;

Fuller, Marina L. Suominen ;

Sherry, Nathaniel ;

Qin, Jinhui ;

McIntyre, N. Stewart ;

Ulaganathan, Jaganathan ;

Carcea, Anatolie G. ;

Newman, Roger C. ;

Kunz, Martin ;

Tamura, Nobumichi .

ACTA MATERIALIA, 2012, 60 (15) :5508-5515

[9] Effect of pressure on the crystal structure of ettringite [J].

Clark, S. M. ;

Colas, B. ;

Kunz, M. ;

Speziale, S. ;

Monteiro, P. J. M. .

CEMENT AND CONCRETE RESEARCH, 2008, 38 (01) :19-26

[10] Si-29 MAS NMR study of the structure of calcium silicate hydrate [J].

Cong, XD ;

Kirkpatrick, RJ .

ADVANCED CEMENT BASED MATERIALS, 1996, 3 (3-4) :144-156

← 1 2 3 4 5 6 →