A comprehensive 3-D modeling of a single planar solid oxide fuel cell

被引:49
作者
Nerat, Marko [1 ]
Juricic, Dani [1 ]
机构
[1] Jozef Stefan Inst, Jamova 39, SI-1000 Ljubljana, Slovenia
关键词
Conversion efficiency; Fuel utilization; Internal methane steam reforming; Solid oxide fuel cell (SOFC); Temperature gradients; Three-dimensional (3-D) modeling; ELECTROCHEMICAL MODEL; SOFC; CONDUCTIVITY; PERFORMANCE; EFFICIENCY; TRANSPORT; METHANE;
D O I
10.1016/j.ijhydene.2015.11.136
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The main motivation of the presented paper is to study the amplitude and location of the maximum temperature (T-max) and maximum temperature gradient (Delta T/Delta x(max)), respectively, as well as the performance parameters of the modeled, single, planar, anode supported, solid oxide fuel cell (SOFC) with internal methane steam reforming at different operating conditions (i.e. current density and inlet velocity of fuel gas). The reforming reaction and locally increased current density lead to inhomogeneous heat generation within the SOFC that results in inhomogeneous distribution of temperature. Due to the latter, a comprehensive, three-dimensional, thermo-fluid model of the SOFC has been developed and implemented in software package COMSOL Multiphysicse (R) 4.3. The simulation results show that the amplitude and location of the T-max and Delta T/Delta x(max) within the modeled SOFC depend on operating conditions. The data about their values can be efficiently used instead of temperature measurements with expensive embedded thermocouples when a realistic, operating SOFC is controlled. The results also show that the current density and the inlet velocity of fuel gas are the key parameters to improve the fuel utilization and the total conversion efficiency. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:3613 / 3627
页数:15
相关论文
共 33 条
  • [1] Anode-supported intermediate temperature direct internal reforming solid oxide fuel cell. I: model-based steady-state performance
    Aguiar, P
    Adjiman, CS
    Brandon, NP
    [J]. JOURNAL OF POWER SOURCES, 2004, 138 (1-2) : 120 - 136
  • [2] Anode-supported intermediate-temperature direct internal reforming solid oxide fuel cell - II. Model-based dynamic performance and control
    Aguiar, P
    Adjiman, CS
    Brandon, NP
    [J]. JOURNAL OF POWER SOURCES, 2005, 147 (1-2) : 136 - 147
  • [3] A three-dimensional numerical model of a single-chamber solid oxide fuel cell
    Akhtar, Naveed
    Decent, Stephen P.
    Loghin, Daniel
    Kendall, Kevin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (20) : 8645 - 8663
  • [4] Experimental and numerical analysis of a radial flow solid oxide fuel cell
    Andreassi, Luca
    Rubeo, Giampiero
    Ubertini, Stefano
    Lunghi, Piero
    Bove, Roberto
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (17) : 4559 - 4574
  • [5] Electrochemical Simulation of Planar Solid Oxide Fuel Cells with Detailed Microstructural Modeling
    Bertei, A.
    Mertens, J.
    Nicolella, C.
    [J]. ELECTROCHIMICA ACTA, 2014, 146 : 151 - 163
  • [6] Experimental real-time optimization of a solid oxide fuel cell stack via constraint adaptation
    Bunin, Gene A.
    Wuillemin, Zacharie
    Francois, Gregory
    Nakajo, Arata
    Tsikonis, Leonidas
    Bonvin, Dominique
    [J]. ENERGY, 2012, 39 (01) : 54 - 62
  • [7] Coal gasification integration with solid oxide fuel cell and chemical looping combustion for high-efficiency power generation with inherent CO2 capture
    Chen, Shiyi
    Lior, Noam
    Xiang, Wenguo
    [J]. APPLIED ENERGY, 2015, 146 : 298 - 312
  • [8] Electrochemical model of the integrated planar solid oxide fuel cell (IP-SOFC)
    Costamagna, P
    Selimovic, A
    Del Borghi, M
    Agnew, G
    [J]. CHEMICAL ENGINEERING JOURNAL, 2004, 102 (01) : 61 - 69
  • [9] Comparison of different current collecting modes of anode supported micro-tubular SOFC through mathematical modeling
    Cui, Daan
    Liu, Lin
    Dong, Yonglai
    Cheng, Mojie
    [J]. JOURNAL OF POWER SOURCES, 2007, 174 (01) : 246 - 254
  • [10] Steady-State and Transient Analysis of a Steam-Reformer Based Solid Oxide Fuel Cell System
    Das, Tuhin
    Narayanan, Sridharan
    Mukherjee, Ranjan
    [J]. JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2010, 7 (01): : 0110221 - 01102210