The rearrangement of phosphitohydrazide ligand [(ArO)2P-NPh-NPh-] into iminophosphoranate anion [(PhN=P(OAr)2-NPh-] {(ArO)2P = [CH2(tBuMeC6H2O)2P]} in coordination sphere of divalent cobalt

被引：10

作者：

Belina, Natalia V. ^{[1
]}

Kornev, Alexander N. ^{[1
]}

Sushev, Vyacheslav V. ^{[1
]}

Fukin, Georgy K. ^{[1
]}

Baranov, Eugene V. ^{[1
]}

Abakumov, Gleb A. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 04期

关键词：

Molecular rearrangements; Phosphazanes; Phosphinohydrazines; Amidoimidophosphoranes; Cobalt(II) complexes; X-ray diffraction; TRANSITION;

D O I：

10.1016/j.jorganchem.2009.11.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of bromophosphite (ArO)(2)PBr{(ArO)(2)P = CH2(6-tBu-4-Me-C6H2O)(2)P} with lithium salt of 1,2-diphenylhydrazine gave phosphitohydrazine (ArO)(2)P-NPh-NPhH (2) in 64% yield. The last one reacted with Co[N(SiMe3)(2)](2) to afford cobalt(II) iminophosphoranate (PhN=P(OAr)(2)-NPh-)(2)Co (3), which is the result of isomerisation of the phosphitohydrazide ligand in coordination sphere of divalent cobalt. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：637 / 641

页数：5

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