An efficient method for catalytic enantioselective addition of diethylzinc to aryl aldehydes by a C2-symmetric chiral imino alcohol

被引：15

作者：

Salehi, Peyman ^{[1
]}

Dabiri, Minoo ^{[2
]}

Kozehgary, Gholamreza ^{[2
]}

Baghbanzadeh, Mostafa ^{[2
]}

机构：

[1] Shaheed Beheshti Univ, Med Plants & Drugs Res Inst, Dept Phytochem, Tehran 1983963113, Iran

[2] Shaheed Beheshti Univ, Fac Sci, Dept Chem, Tehran 1983963113, Iran

来源：

TETRAHEDRON-ASYMMETRY | 2009年 / 20卷 / 22期

关键词：

AROMATIC-ALDEHYDES; CARBONYL-COMPOUNDS; AMINO ALCOHOLS; DIALKYLZINCS; DERIVATIVES; REAGENTS; LIGANDS;

D O I：

10.1016/j.tetasy.2009.10.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enantioselective alkylation of aryl aldehydes with diethylzinc in the presence of a C-2-symmetric chiral ligand derived from 2-hydroxy-3-pinanone was achieved at room temperature with high enantiomeric excesses. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2609 / 2611

页数：3

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