An efficient method for catalytic enantioselective addition of diethylzinc to aryl aldehydes by a C2-symmetric chiral imino alcohol

被引：15
作者：
Salehi, Peyman [1 ]
Dabiri, Minoo [2 ]
Kozehgary, Gholamreza [2 ]
Baghbanzadeh, Mostafa [2 ]
机构：
[1] Shaheed Beheshti Univ, Med Plants & Drugs Res Inst, Dept Phytochem, Tehran 1983963113, Iran
[2] Shaheed Beheshti Univ, Fac Sci, Dept Chem, Tehran 1983963113, Iran
来源：
TETRAHEDRON-ASYMMETRY | 2009年 / 20卷 / 22期
关键词：
AROMATIC-ALDEHYDES; CARBONYL-COMPOUNDS; AMINO ALCOHOLS; DIALKYLZINCS; DERIVATIVES; REAGENTS; LIGANDS;
D O I：
10.1016/j.tetasy.2009.10.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantioselective alkylation of aryl aldehydes with diethylzinc in the presence of a C-2-symmetric chiral ligand derived from 2-hydroxy-3-pinanone was achieved at room temperature with high enantiomeric excesses. (C) 2009 Elsevier Ltd. All rights reserved.
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页码：2609 / 2611
页数：3
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