Micellar effect in hydroformylation of high olefin catalysed by water-soluble rhodium complexes associated with sulfonated diphosphines

被引：29
作者：
Giménez-Pedrós, M
Aghmiz, A
Claver, C
Masdeu-Bultó, AM
Sinou, D
机构：
[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, E-43005 Tarragona, Spain
[2] Univ Lyon 1, CPE Lyon, CNRS, Lab Synth Asymetr, F-69622 Villeurbanne, France
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 200卷 / 1-2期
关键词：
hydroformylation; aqueous systems; sulfonated diphosphines; micellar effect;
D O I：
10.1016/S1381-1169(03)00036-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
High linear alkenes (1-octene and 1-decene) have been hydroformylated using water-soluble rhodium complexes associated with sulfonated diphosphines in the presence of ionic surfactants or methanol. In all cases, the hydroformylation activities were higher than in experiments without additives. The selectivity in aldehydes was higher when we used cetyltrimethylammonium hydrogensulfate (CTAHSO(4)) as the surfactant or methanol as the co-solvent. (C) 2003 Elsevier Science B.V. All rights reserved.
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收藏
页码：157 / 163
页数：7
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