Application of cellulose modified with p-aminobenzoic groups in preconcentration system for determination of Cu, Fe, Ni, and Zn in fuel ethanol samples by flame atomic absorption spectrometry

被引:24
作者
de Castro, G. R.
de Oliveira, J. D.
Alcantara, I. L.
Roldan, P. S.
Padilha, C. C. F.
Prado, A. G. S.
Padilha, P. M.
机构
[1] Univ Estadual Paulista, UNESP, Dept Fis & Biofis, Inst Biociencias, BR-18610000 Botucatu, SP, Brazil
[2] Univ Estadual Paulista, UNESP, Fac Engn Ilha Solteira, Ilha Solteira, SP, Brazil
[3] Univ Estadual Paulista, UNESP, Dept Quim Analit, Inst Quim, Araraquara, SP, Brazil
[4] Univ Sao Paulo, Ctr Energia Nucl Agr, Piracicaba, SP, Brazil
[5] Univ Brasilia, UNB, Dept Quim Inorgan, Inst Quim, Brasilia, DF, Brazil
基金
巴西圣保罗研究基金会;
关键词
cellulose chemically modified; p-aminobenzoic groups; preconcentration; adsorption;
D O I
10.1080/01496390701242061
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cellulose chemically modified with p-aminobenzoic groups, abbreviated as Cel-PAB, was used for preconcentration of copper, iron, nickel, and zinc from ethanol fuel, normally used in Brazil as engine fuel. The surface characteristics and the surface area of the cellulose were obtained before and after chemical modification using FT-IR, elemental analysis, and surface area analysis (B.E.T.). The retention and recovery of the analyte elements were studied by applying batch and column techniques.
引用
收藏
页码:1325 / 1340
页数:16
相关论文
共 21 条
[1]   IMMOBILIZED 3-AMINOPYRIDINE ON SILICA - ADSORPTION OF SOME METAL(II) CHLORIDES IN NON-AQUEOUS SOLUTIONS [J].
AIROLDI, C ;
GONCALVES, AS .
COLLOIDS AND SURFACES, 1987, 28 (2-4) :199-208
[2]   Determination of Cu, Ni and Pb in aqueous medium by FAAS after pre-concentration on 2-aminothiazole modified silica gel [J].
Alcântara, IL ;
dos Santos Roldan, P ;
Margionte, MAL ;
Castro, GR ;
Padilha, CCF ;
Florentino, AD ;
Padilha, PD .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2004, 15 (03) :366-371
[3]  
Alcântara TL, 2004, ANAL SCI, V20, P1029
[4]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[5]   Sorption and preconcentration of metal ions in ethanol solution with a silica gel surface chemically modified with benzimidazole [J].
Dias, NL ;
Gushikem, Y ;
Polito, WL ;
Moreira, JC ;
Ehirim, EO .
TALANTA, 1995, 42 (11) :1625-1630
[6]  
Gomes LAD, 1998, J BRAZIL CHEM SOC, V9, P494
[7]   ADSORPTION OF METAL-IONS FROM ETHANOL ON AN IMINOSALICYL-MODIFIED SILICA-GEL [J].
KUBOTA, LT ;
MOREIRA, JC ;
GUSHIKEM, Y .
ANALYST, 1989, 114 (11) :1385-1388
[8]   Sorption and preconcentration of metal ions on silica gel modified with 2,5-dimercapto-1,3,4-thiadiazole [J].
Lessi, P ;
Dias, NL ;
Moreira, JC ;
Campos, JTS .
ANALYTICA CHIMICA ACTA, 1996, 327 (02) :183-190
[9]   PRECONCENTRATION OF METAL-IONS ON SILICA-GEL MODIFIED WITH 3(1-IMIDAZOLYL)PROPYL GROUPS [J].
MOREIRA, JC ;
GUSHIKEM, Y .
ANALYTICA CHIMICA ACTA, 1985, 176 (OCT) :263-267
[10]   Preconcentration of heavy metals ions from aqueous solutions by means of cellulose phosphate: an application in water analysis [J].
Padilha, PD ;
Rocha, JC ;
Moreira, JC ;
Campos, JTD ;
Federici, CD .
TALANTA, 1997, 45 (02) :317-323