Molecular beam scattering experiments probing the interaction of Cl2 with simple molecules (D2, O2, D2O, ND3)

被引：1

作者：

Cappelletti, David ^{[1
]}

Falcinelli, Stefano ^{[2
]}

Pirani, Fernando ^{[1
]}

机构：

[1] Univ Perugia, Dipartimento Chim Biol & Biotecnol, Via Elce Sotto 8, I-06123 Perugia, Italy

[2] Univ Perugia, Dipartimento Ingn Civile & Ambientale, Via G Duranti 93, I-06215 Perugia, Italy

来源：

CHEMICAL PHYSICS LETTERS | 2021年 / 771卷

关键词：

Halogen bond; Charge transfer; Molecular beam scattering; Chlorine; ELASTIC CROSS-SECTIONS; CHARGE-TRANSFER; HALOGEN BOND; OPEN-SHELL; WATER; NE; COLLISIONS; CHLORINE; BROMINE; SYSTEMS;

D O I：

10.1016/j.cplett.2021.138521

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular beam experiments for the scattering of D2, O2, D2O, and ND3 by Cl2 have been carried out to probe the involved intermolecular interaction and the quantum ?glory? interference effect has been observed for all the systems. Simple and reliable interaction potentials, defined as a combination of an anisotropic van der Waals, polar flattening, charge transfer and electrostatic terms have been obtained.

引用

页数：6