Nitration of deactivated aromatic compounds via mechanochemical reaction

被引：11
作者：
Wu, Jian-Wei [1 ]
Zhang, Pu [1 ]
Guo, Zhi-Xin [1 ]
机构：
[1] Renmin Univ China, Dept Chem, Beijing 100873, Peoples R China
来源：
TETRAHEDRON LETTERS | 2021年 / 72卷
关键词：
Mechanochemistry; Nitration; Fe(NO3)(3)center dot 9H(2)O; P2O5; KYODAI-NITRATION; NITRIC-ACID; CHLOROBENZENE; MONONITRATION; PARAMETERS; PHENOLS; TOLUENE; MILD; C-60; MONO;
D O I：
10.1016/j.tetlet.2021.153087
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of deactivated arenes were nitrated to their corresponding nitro derivatives in excellent yields under high-speed ball milling condition using Fe(NO3)(3)center dot 9H(2)O/P2O5 as nitrating reagent. A radical involved mechanism was proposed for this facial, eco-friendly, safe, and effective nitration reaction. (C) 2021 Elsevier Ltd. All rights reserved.
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页数：5
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