Self-assembly of Pd2L2 Metallacycles Owning Diversely Functionalized Racemic Ligands

被引：16

作者：

Rama, Tamara ^{[1
,2
]}

Alvarino, Cristina ^{[1
,2
]}

Domarco, Olaya ^{[1
,2
]}

Platas-Iglesias, Carlos ^{[1
,2
]}

Blanco, Victor ^{[3
]}

Garcia, Marcos D. ^{[1
,2
]}

Peinador, Carlos ^{[1
,2
]}

Quintela, Jose M. ^{[1
,2
]}

机构：

[1] Univ A Coruna, Fac Ciencias, Dept Quim Fundamental, E-15071 La Coruna, Spain

[2] Univ A Coruna, Fac Ciencias, Ctr Invest Cient Avanzadas, E-15071 La Coruna, Spain

[3] Univ Granada, Fac Ciencias, Dept Quim Organ, Campus Fuentenueva S-N, E-18071 Granada, Spain

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 05期

关键词：

PD-II; NONCOVALENT INTERACTIONS; COORDINATION; COMPLEXATION; CATENATION; DISCRETE; CLICK; CHLORIDE; SYMMETRY; DESIGN;

D O I：

10.1021/acs.inorgchem.5b02650

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present herein the efficient palladium(II)-directed self-assembly in water of a series of nine new diversely functionalized metallacycles, owning hydroxy/alkoxycarbonyl/azidoalkyl exo pendant groups attached to ditopic N-monoalkyl/aryl-4,4'-bipyridinium/2,7-diazapyrenium ligands. The highly convergent and versatile synthetic route for the ligands uses the Zincke reaction between (dinitrophenyl)-bipyridinium/diazapyrenium salts and racemic amines as the key step. The stereochemical outcome of the self-assembly of the Pd2L2 species is discussed on the basis of density functional theory quantum-chemical calculations.

引用

页码：2290 / 2298

页数：9

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