Ceramic carbon electrode-based anodes for use in the Cu-Cl thermochemical cycle

被引：22

作者：

Ranganathan, Santhanam ^{[1
]}

Easton, E. Bradley ^{[1
]}

机构：

[1] Univ Ontario Inst Technol, Fac Sci, Oshawa, ON L1H 7K4, Canada

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2010年 / 35卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Ceramic carbon electrodes; Nuclear-based hydrogen production; Thermochemical copper-chloride cycle; Electrolysis; HYDROGEN-PRODUCTION; COMPOSITE;

D O I：

10.1016/j.ijhydene.2009.08.085

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have investigated CCE materials prepared using 3-aminopropyl trimethoxysilane. Electrochemical experiments were performed to characterize their suitability as anode electrode materials for use in the electrochemical step of the Cu-Cl thermochemical cycle. CCE-based electrodes vastly outperform a bare carbon electrode. Optimization of the organosilicate loading revealed maximum electrode performance was achieved with 36 wt% and was explained in terms of the optimal balance of active area and anion transport properties. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

引用

页码：4871 / 4876

页数：6

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