Efficient Synthesis of Lactic Acid by Aerobic Oxidation of Glycerol on Au-Pt/TiO2 Catalysts

被引：216
作者：
Shen, Yihong [1 ]
Zhang, Shenghong [1 ]
Li, Hongjia [1 ]
Ren, Yuan [1 ]
Liu, Haichao [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Stable & Unstable Speci, Beijing 100871, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 25期
基金：
中国国家自然科学基金;
关键词：
biomass; gold; heterogeneous catalysis; lactic acid; platinum; SUPPORTED GOLD CATALYSTS; SELECTIVE OXIDATION; METAL-CATALYSTS; BIMETALLIC CATALYSTS; MOLECULAR-OXYGEN; AU CATALYSTS; CHEMICALS; BIOMASS; FUELS; HYDROGENOLYSIS;
D O I：
10.1002/chem.201000740
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical equation presented) Go for the burn! A one-pot approach to the efficient synthesis of lactic acid through the aerobic oxidation of glycerol in the presence of bases at an atmospheric pressure of O2 is reported, which combines two consecutive reactions, including oxidative dehydrogenation of glycerol to its dehydrogenated intermediates and their subsequent isomerization (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7368 / 7371
页数：4
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共 37 条
  • [1] Improved utilisation of renewable resources: New important derivatives of glycerol
    Behr, Arno
    Eilting, Jens
    Irawadi, Ken
    Leschinski, Julia
    Lindner, Falk
    [J]. GREEN CHEMISTRY, 2008, 10 (01) : 13 - 30
  • [2] Selective oxidation of alcohols and aldehydes on metal catalysts
    Besson, M
    Gallezot, P
    [J]. CATALYSIS TODAY, 2000, 57 (1-2) : 127 - 141
  • [3] Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals
    Bianchi, CL
    Canton, P
    Dimitratos, N
    Porta, F
    Prati, L
    [J]. CATALYSIS TODAY, 2005, 102 : 203 - 212
  • [4] Oxidation of glycerol using supported Pt, Pd and Au catalysts
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Kiely, CJ
    Hutchings, GJ
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) : 1329 - 1336
  • [5] Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Hutchings, GJ
    [J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 696 - 697
  • [6] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals
    Chheda, Juben N.
    Huber, George W.
    Dumesic, James A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) : 7164 - 7183
  • [7] Bimetallic Pt-Metal catalysts for the decomposition of methanol: Effect of secondary metal on the oxidation state, activity, and selectivity of Pt
    Croy, Jason R.
    Mostafa, S.
    Hickman, L.
    Heinrich, H.
    Roldan Cuenya, B.
    [J]. APPLIED CATALYSIS A-GENERAL, 2008, 350 (02) : 207 - 216
  • [8] Au-Pt alloy nanocrystals incorporated in silica films
    De, G
    Rao, CNR
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (08) : 891 - 894
  • [9] Use of renewables for the production of chemicals: Glycerol oxidation over carbon supported gold catalysts
    Demirel, S.
    Lehnert, K.
    Lucas, M.
    Claus, P.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 70 (1-4) : 637 - 643
  • [10] Liquid phase oxidation of glycerol over carbon supported gold catalysts
    Demirel-Gülen, S
    Lucas, M
    Claus, P
    [J]. CATALYSIS TODAY, 2005, 102 : 166 - 172
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