Diastereo- and Enantioselective Valorization of Cyclic Organic Carbonates

被引：13

作者：

Kleij, Arjan W. ^{[1
,2
]}

Whiteoak, Christopher J. ^{[3
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

[3] Univ Girona, IQCC, Girona 17071, Spain

来源：

CHEMCATCHEM | 2015年 / 7卷 / 01期

关键词：

asymmetric catalysis; cyclic carbonates; decarboxylation; palladium; synthetic methods; DECARBOXYLATIVE CYCLOADDITION; VINYLETHYLENE CARBONATES; CO2; CONSTRUCTION; ALDEHYDE; FIXATION; DIOXIDE;

D O I：

10.1002/cctc.201402801

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Breaking the cycle: The formation of cyclic organic carbonates is well studied, although reactions utilizing these versatile precursors are relatively limited. The conversions highlighted here demonstrate the use of these organic carbonates as valuable synthetic precursors, providing facile access to high-potential synthons with excellent stereochemical control. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：51 / 53

页数：3

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