Phase equilibria in the Li-Ti-O system and physical properties of Li2TiO3

被引：121

作者：

Kleykamp, H ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, Inst Mat Forsch 1, D-76021 Karlsruhe, Germany

来源：

FUSION ENGINEERING AND DESIGN | 2002年 / 61-62卷

关键词：

phase equilibria; Li-Ti-O system; thermal properties;

D O I：

10.1016/S0920-3796(02)00120-5

中图分类号：

TL [原子能技术]; O571 [原子核物理学];

学科分类号：

0827 ; 082701 ;

摘要：

The phase equilibria of the pseudo-binary Li2O-TiO2 system and the stoichiometry shift of Li2TiO3 during the Li transmutation process are investigated. The structural properties, the thermal expansion, enthalpy, heat capacity, enthalpy of transformation and melting, thermal conductivity and the vapourisation behaviour of Li2TiO3 are assessed. The ternary Li-Ti-O system is treated with emphasis to the characteristic of Li2TiO3 under reducing conditions. The phase is reduced to LiTiO2 with the Ti valence +3 due to its transition metal character. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：361 / 366

页数：6

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