Synthesis and Crystal Structure of (NH4)3 [UO2(CH3COO)3]2[UO2(CH3 COO)(NCS)2(H2O)]

被引：1

作者：

Serezhkina, L. B. ^{[1
]}

Peresypkina, E. V. ^{[2
]}

Virovets, A. V. ^{[2
]}

Karasev, M. O. ^{[1
]}

机构：

[1] Samara State Univ, Samara 443011, Russia

[2] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 01期

关键词：

Uranium; Crystallography Report; Ammonium Cation; Uranium Atom; Uranyl Complex;

D O I：

10.1134/S1063774510010050

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Single crystals of the compound (NH4)(3)[UO2(CH3COO)(3)](2)[UO2(CH3COO)(NCS)(2)(H2O)] (I) are synthesized, and their structure is investigated using X-ray diffraction. Compound I crystallizes in the monoclinic system with the unit cell parameters a = 18.3414(6) angstrom, b = 16.3858(7) angstrom, c = 12.4183(5) angstrom, beta = 92.992(1)degrees, space group C2/c, Z - 4, V - 3727.1(3) angstrom(3), and R - 0.0253. The uranium-containing structural units of crystals I are mononuclear complexes of two types with an island structure, i.e., the [UO2(CH3COO)(3)](-) anionic complexes belonging to the crystal-chemical group AB(3)(01) (A = UO22+, B-01 = CH3COO-) of the uranyl complexes and the [UO2(CH3COO)(NCS)(2)(H2O)](-) anionic complexes belonging to the crystal-chemical group AB(01)M(3)(1) (A = UO22+, B-01 = CH3COO-, M-1 = NCS- or H2O).

引用

页码：19 / 23

页数：5

共 50 条

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