Solubilities in aqueous solutions of the sodium salts of succinic and glutaric acid with and without ammonium sulfate

被引:3
作者
Beyer, Keith D. [1 ]
Buttke, Lukas G. [1 ]
机构
[1] Univ Wisconsin, Dept Chem & Biochem, La Crosse, WI 54601 USA
基金
美国国家科学基金会;
关键词
Ammonium sulphate; Sodium malonate; Sodium succinate; Aqueous; Phase diagram; Solubility; DUST PARTICLES; OXALIC-ACID; AEROSOLS; WATER; OXIDATION; CHLORIDE; ORGANICS; CIRRUS;
D O I
10.1016/j.jct.2018.06.002
中图分类号
O414.1 [热力学];
学科分类号
摘要
The aqueous solubility of the least soluble salts in mixtures of sodium hydrogen succinate, sodium succinate, sodium hydrogen glutarate, and sodium glutarate with and without ammonium sulfate present has been studied. Solubility temperatures were determined in solutions of known concentration using Differential Scanning Calorimetry. The identity of the least soluble solid was determined by a combination of X-ray crystallography and infrared spectroscopy. The identified solids included ammonium sulfate, sodium sulfate, sodium ammonium sulfate dihydrate (lecontite), sodium hydrogen succinate, sodium succinate hexahydrate, sodium hydrogen glutarate dihydrate, and ammonium hydrogen glutarate. Of the 16 series of solutions studied, lecontite was most frequently the least soluble solid. (C) 2018 Elsevier Ltd.
引用
收藏
页码:189 / 199
页数:11
相关论文
共 41 条
  • [1] [Anonymous], 2020, Gothenburg Protocol to reduce transboundary air pollution, DOI DOI 10.5860/CHOICE.44-4512
  • [2] [Anonymous], SOV PHYS CRYSTALLOGR
  • [3] [Anonymous], 1971, J CRYST MOL STRUCT, DOI DOI 10.1007/BF01198531
  • [5] SOLUBILITY OF OXALIC, MALONIC, SUCCINIC, ADIPIC, MALEIC, MALIC, CITRIC, AND TARTARIC-ACIDS IN WATER FROM 278.15-K TO 338.15-K
    APELBLAT, A
    MANZUROLA, E
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (03) : 317 - 320
  • [6] THE OPTICAL-ACTIVITY AND ABSOLUTE OPTICAL CHIRALITY OF NANH4SO4.2H2O
    ARZT, S
    GLAZER, AM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1994, 50 : 425 - 431
  • [7] Phase Diagrams and Water Activities of Aqueous Dicarboxylic Acid Systems of Atmospheric Importance
    Beyer, Keith D.
    Friesen, Katherine
    Bothe, Jameson R.
    Palet, Benjamin
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (46) : 11704 - 11713
  • [8] Solubility of the Sodium and Ammonium Salts of Oxalic Acid in Water with Ammonium Sulfate
    Buttke, Lukas G.
    Schueller, Justin R.
    Pearson, Christian S.
    Beyer, Keith D.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (32) : 6424 - 6433
  • [9] Clarifying the Dominant Sources and Mechanisms of Cirrus Cloud Formation
    Cziczo, Daniel J.
    Froyd, Karl D.
    Hoose, Corinna
    Jensen, Eric J.
    Diao, Minghui
    Zondlo, Mark A.
    Smith, Jessica B.
    Twohy, Cynthia H.
    Murphy, Daniel M.
    [J]. SCIENCE, 2013, 340 (6138) : 1320 - 1324
  • [10] Dicarboxylic acids, oxoacids, benzoic acid, α-dicarbonyls, WSOC, OC, and ions in spring aerosols from Okinawa Island in the western North Pacific Rim: size distributions and formation processes
    Deshmukh, Dhananjay K.
    Kawamura, Kimitaka
    Lazaar, Manuel
    Kunwar, Bhagawati
    Boreddy, Suresh K. R.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2016, 16 (08) : 5263 - 5282