Crystal structures, one- and two-photon excited fluorescence of two complexes based on D-π-A structural 2,2-bipyridine derivative

被引:3
作者
Jin, Feng [1 ]
Ye, Zhifeng [1 ]
Wang, Mimi [1 ]
Li, Min [1 ]
Zha, Quanjun [1 ]
Geng, Ying [1 ]
Li, Weilong [1 ]
Liu, Zhaodi [1 ]
Liao, Rongbao [1 ]
Tao, Dongliang [1 ]
Tian, Yupeng [2 ]
机构
[1] Fuyang Normal Univ, Coll Chem & Mat Engn, Fuyang 236037, Peoples R China
[2] Anhui Univ, Coll Chem & Chem Engn, Hefei 230039, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Two-photon excited fluorescence; Two-photon absorption cross-section; Complex; Bioimaging; OPTICAL-PROPERTIES; DFT CALCULATION; ZN(II) COMPLEX; ABSORPTION; EXCITATION; SERIES;
D O I
10.1016/j.dyepig.2019.107669
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
By coordination of an electron donor-pi-bridge-electron acceptor (D-pi-A) optical functional organic ligand (L) with ZnBr2 and HgBr2, two fluorescent complexes ZnBr2L (1) and HgBr2L (2) were obtained. The structures of them were solved by single crystal X-ray diffraction analysis. Study of linear and nonlinear optical properties has shown that the complexes exhibit excellent one- and two-photon excited fluorescence and large two-photon absorption cross-section values. Dye 1 shows the potential application in fluorescence microscopy bioimaging.
引用
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页数:6
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