Trifunctional Metal-Organic Framework Catalyst for CO2 Conversion into Cyclic Carbonates

被引：47

作者：

Liu, Shuo ^{[1
]}

Gao, Ming-Liang ^{[1
]}

Zhang, Yue ^{[1
]}

Liu, Lin ^{[1
]}

Han, Zheng-Bo ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 09期

基金：

中国国家自然科学基金;

关键词：

HETEROGENEOUS CATALYSTS; CAPTURE; DIOXIDE;

D O I：

10.1021/acs.inorgchem.1c00536

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we reported a facile strategy for the preparation of trifunctional ionic metal-organic frameworks (MOFs) incorporating imidazolium cation functionalities. This strategy exploits the Debus-Radziszewski reaction to create the cationic imidazole ring by postsynthetic modification, meanwhile introducing exchangeable counteranions. On the basis of this strategy, MIL-101-IMOH-Br- has been synthesized, which combines Lewis acidic sites, Bronsted acidic sites, and nucleophilic centers to achieve catalysis for the carbon dioxide-epoxide cycloaddition into cyclocarbonate without any cocatalyst and solvent.

引用

页码：6152 / 6156

页数：5

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