Design strategies of highly selective nickel catalysts for H2 production via hydrous hydrazine decomposition: a review

被引：77

作者：

He, Lei ^{[1
]}

Liang, Binglian ^{[1
,2
]}

Huang, Yanqiang ^{[1
]}

Zhang, Tao ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

NATIONAL SCIENCE REVIEW | 2018年 / 5卷 / 03期

基金：

中国国家自然科学基金;

关键词：

hydrazine; selectivity; H-2; catalyst; nickel; NI-PT NANOPARTICLES; ROOM-TEMPERATURE; EFFICIENT CATALYSTS; ALKALINE-SOLUTION; RHODIUM NANOPARTICLES; AMBIENT CONDITIONS; AQUEOUS-SOLUTION; ALLOY CATALYSTS; GENERATION; STORAGE;

D O I：

10.1093/nsr/nwx123

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Hydrazine, a widely used liquid propellant, has the potential to be employed as a hydrogen source in certain instances and has therefore attracted considerable attention; consequently, the complete decomposition of hydrazine with 100% H-2 selectivity under mild conditions has become the current research focus for catalyst design. In this review, the strategies for the design of efficient catalysts are summarized for complete hydrazine decomposition. The first part of this review introduces the mechanism of hydrazine decomposition, while the second part illustrates the key factors influencing the H-2 selectivity of nickel catalysts, including the effects of alloying, alkali promoter addition and strong metal-support interactions. Finally, the critical elements of catalyst design employed in industrial applications are analyzed.

引用

页码：356 / 364

页数：9

共 71 条

[1] Hydrazine (N2H4) adsorption on Ni(100) - Density functional theory investigation [J].

Agusta, Mohammad Kemal ;

David, Melanie ;

Nakanishi, Hiroshi ;

Kasai, Hideaki .

SURFACE SCIENCE, 2010, 604 (3-4) :245-251

[2] SURFACE-CHEMISTRY OF HYDRAZINE ON PT(111) [J].

ALBERAS, DJ ;

KISS, J ;

LIU, ZM ;

WHITE, JM .

SURFACE SCIENCE, 1992, 278 (1-2) :51-61

[3]

Batonneau Y., 2008, HDB HETEROGENEOUS CA

[4] Trimetallic NiFePd nanoalloy catalysed hydrogen generation from alkaline hydrous hydrazine and sodium borohydride at room temperature [J].

Bhattacharjee, Debaleena ;

Dasgupta, Subrata .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (48) :24371-24378

[5] High performance nickel-palladium nanocatalyst for hydrogen generation from alkaline hydrous hydrazine at room temperature [J].

Bhattacharjee, Debaleena ;

Mandal, Kaustab ;

Dasgupta, Subrata .

JOURNAL OF POWER SOURCES, 2015, 287 :96-99

[6] CATALYTIC DECOMPOSITION OF NITROGEN-15-LABELED HYDRAZINE ON MGO-SUPPORTED IRON [J].

BLOCK, J ;

SCHULZEK.G .

JOURNAL OF CATALYSIS, 1973, 30 (02) :327-329

[7] Ni-Pt nanoparticles supported on MIL-101 as highly efficient catalysts for hydrogen generation from aqueous alkaline solution of hydrazine for chemical hydrogen storage [J].

Cao, Nan ;

Su, Jun ;

Luo, Wei ;

Cheng, Gongzhen .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (18) :9726-9734

[8] Rh-Ni nanoparticles immobilized on Ce(OH)CO3 nanorods as highly efficient catalysts for hydrogen generation from alkaline solution of hydrazine [J].

Chen, Jianmin ;

Yao, Qilu ;

Zhu, Jia ;

Chen, Xiangshu ;

Lu, Zhang-Hui .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (06) :3946-3954

[9] A density functional theory investigation of the molecular and dissociative adsorption of hydrazine on defective copper surfaces [J].

Daff, Thomas D. ;

de Leeuw, Nora H. .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (43) :23210-23220

[10]

deMedeiros JE, 1998, BRAZ J CHEM ENG, V15, P126

← 1 2 3 4 5 6 7 8 →