Analysis of rotation-vibration relative equilibria on the example of a tetrahedral four atom molecule

被引:14
作者
Efstathiou, K [1 ]
Sadovskii, DA [1 ]
Zhilinskii, BI [1 ]
机构
[1] Univ Littoral, CNRS, UMR 8101, F-59140 Dunkerque, France
来源
SIAM JOURNAL ON APPLIED DYNAMICAL SYSTEMS | 2004年 / 3卷 / 03期
关键词
small vibrations; vibration-rotation of molecules; spherical top; relative equilibria; 1 : 1 : 1 resonant oscillator; normalization; reduction; bifurcations; orbit space; finite group action; reversing symmetry; Molien generating function; integrity basis;
D O I
10.1137/030600015
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
We study relative equilibria ( RE) of a nonrigid molecule, which vibrates about a well-defined equilibrium configuration and rotates as a whole. Our analysis unifies the theory of rotational and vibrational RE. We rely on the detailed study of the symmetry group action on the initial and reduced phase space of our system and consider the consequences of this action for the dynamics of the system. We develop our approach on the concrete example of a four-atomic molecule A(4) with tetrahedral equilibrium configuration, a dynamical system with six vibrational degrees of freedom. Further applications and illustrations of our results can be found in [ van Hecke et al., Eur. Phys. J. D At. Mol. Opt. Phys., 17 ( 2001), pp. 13 - 35].
引用
收藏
页码:261 / 351
页数:91
相关论文
共 112 条
  • [1] Abraham R., 1978, Foundations of mechanics
  • [2] Aliev M. R., 1985, MOL SPECTROSCOPY MOD, P1, DOI DOI 10.1016/B978-0-12-580643-5.50006-3
  • [3] AMAT G, 1971, ROTATION VIBRATIONS, P41902
  • [4] ANOLD VI, 1989, GRAD TEXTS MATH, V60, P41902
  • [5] [Anonymous], 1992, Spherical Top Spectra
  • [6] Arnold V. I., 1985, ENCY MATH SCI, V3, P5
  • [7] ARNOLD VI, 1997, ENCY MATH, V3, P41902
  • [8] ARNOLD VI, 1988, FUND PRINCIPLES MATH, V250, P41902
  • [9] Biedenharn L. S., 1981, ANGULAR MOMENTUM QUA
  • [10] High-resolution Fourier transform infrared spectroscopy and analysis of the ν3 fundamental band of P4
    Boudon, V
    Mkadmi, EB
    Bürger, H
    Pierre, G
    [J]. CHEMICAL PHYSICS LETTERS, 1999, 305 (1-2) : 21 - 27