Direct Synthesis of Photocatalytically Active Rutile TiO2 Nanorods Partly Decorated with Anatase Nanoparticles

被引：98

作者：

Kandiel, Tarek A. ^{[1
]}

Dillert, Ralf ^{[1
]}

Feldhoff, Armin ^{[2
]}

Bahnemann, Detlef W. ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Tech Chem, D-30167 Hannover, Germany

[2] Leibniz Univ Hannover, Inst Phys Chem & Elektrochem, D-30167 Hannover, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 11期

关键词：

TITANIUM-DIOXIDE; HYDROTHERMAL SYNTHESIS; TEMPERATURE SYNTHESIS; OXIDE NANOCRYSTALS; THIN-FILM; PHASE; SIZE; ACETALDEHYDE; DEGRADATION; HYDROLYSIS;

D O I：

10.1021/jp912008k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

TiO2 rutile nanorods either decorated with anatase nanoparticles or pure have been prepared via it facile single-step hydrothermal method using commercially available aqueous solution of titanium bis(ammonium lactate) dihydroxide at natural pH (similar to 8.0) without any additives. The obtained powders have been characterized by X-ray diffraction, field-emission scanning, electron microscopy, high-resolution transmission electron microscopy, UV-vis diffuse reflectance spectroscopy, and nitrogen adsorption. The photocatalytic activities have been evaluated for the gas-phase decomposition of acetaldehyde Under UV(A) illumination. The results revealed that TiO2 rutile nanorods decorated with anatase nanoparticles exhibit a higher photocatalytic activity than those embedded in anatase nanoparticles or without ally anatase contact. This behavior is explained by the better charge carrier separation in the Case Of anatase rutile mixtures.

引用

页码：4909 / 4915

页数：7

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