Photopolymerized Lipids Self-Assembly for the Solubilization of Carbon Nanotubes

被引:17
作者
Contal, Emmanuel [1 ]
Morere, Alexandre [1 ]
Thauvin, Cedric [1 ]
Perino, Aurelia [1 ]
Meunier, Stephane [1 ]
Mioskowski, Charles [1 ]
Wagner, Alain [1 ]
机构
[1] Fac Pharm, Lab Funct Chemosyst, UMR 7199, F-67400 Illkirch Graffenstaden, France
关键词
DISPERSION; SEPARATION; POLYMER;
D O I
10.1021/jp1010007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Because they have a great propensity to aggregation in water, solubilization of carbon nanotubes (CNTs) in aqueous media remains an important challenge. Our laboratory has reported the self-organization of synthetic lipids into hemi-micellar structures at the carbon nanotubes surface. Subsequent stabilization of these carbon nanotube/lipid assembly (CNT/LA) constructs is achieved through photopolymerization of the diyne motif of the pentacosa-10.12-diynoic lipids. Herein we investigate the scope of this coating procedure for CNT solubilization. A panel of CNTs was selected according to the method of production and the characteristics of CNTs. The study revealed that it is possible to reach a complete lipid adsorption. The TEM analyses demonstrate that lipid hemi-micellar self-assemblies can be formed around SWNTs as well as around DWNTs and MWNTs, particularly for carbon nanotubes produced by the arc-discharged method. The nanotube suspensions show a very good stability and are homogeneous for months even at a high nanotubes concentration.
引用
收藏
页码:5718 / 5722
页数:5
相关论文
共 50 条
[41]   Single-Stranded DNA Functionalized Single-Walled Carbon Nanotubes for Microbiosensors via Layer-by-Layer Electrostatic Self-Assembly [J].
Kang, Zhuo ;
Yan, Xiaoqin ;
Zhang, Yue ;
Pan, Jing ;
Shi, Jin ;
Zhang, Xiaohui ;
Liu, Yi ;
Choi, Jong Hyun ;
Porterfield, D. Marshall .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (06) :3784-3789
[42]   Dynamic and Reversible Self-Assembly of Photoelectrochemical Complexes Based on Lipid Bilayer Disks, Photosynthetic Reaction Centers, and Single-Walled Carbon Nanotubes [J].
Boghossian, Ardemis A. ;
Choi, Jong Hyun ;
Ham, Moon-Ho ;
Strano, Michael S. .
LANGMUIR, 2011, 27 (05) :1599-1609
[43]   On-Chip Chemical Self-Assembly of Semiconducting Single-Walled Carbon Nanotubes (SWNTs): Toward Robust and Scale Invariant SWNTs Transistors [J].
Derenskyi, Vladimir ;
Gomulya, Widianta ;
Talsma, Wytse ;
Salazar-Rios, Jorge Mario ;
Fritsch, Martin ;
Nirmalraj, Peter ;
Riel, Heike ;
Allard, Sybille ;
Scherf, Ullrich ;
Loi, Maria A. .
ADVANCED MATERIALS, 2017, 29 (23)
[44]   Grafting of multi-sensitive PDMAEMA brushes onto carbon nanotubes by ATNRC: tunable thickening/thinning and self-assembly behaviors in aqueous solutions [J].
Tan, Yeqiang ;
Zhang, Wenqian ;
Li, Yanhui ;
Xia, Yanzhi ;
Sui, Kunyan .
RSC ADVANCES, 2016, 6 (95) :92305-92315
[45]   Ultrasound directed self-assembly processing of nanocomposite materials with ultra-high carbon nanotube weight fraction [J].
Greenhall, J. ;
Homel, L. ;
Raeymaekers, B. .
JOURNAL OF COMPOSITE MATERIALS, 2019, 53 (10) :1329-1336
[46]   Directed Self-Assembly: Expectations and Achievements [J].
Kumar, Prashant .
NANOSCALE RESEARCH LETTERS, 2010, 5 (09) :1367-1376
[47]   Self-assembly micro optical filter [J].
Zhang, P ;
Le, K ;
Malalur-Nagaraja-Rao, S ;
Hsu, LC ;
Chiao, JC .
PHOTONICS: DESIGN, TECHNOLOGY, AND PACKAGING II, 2006, 6038
[48]   Solubilization, characterization, and protein coupling analysis to multiwalled carbon nanotubes [J].
Gloria, Juliane ;
Brito, Walter ;
Gandarilla, Ariamna ;
Larrude, Duniesky ;
Carlos, Jacqueline ;
Araujo, Felipe ;
Almeida, Maria Edilene ;
Manzato, Lizandro ;
Mariuba, Luis Andre Morais .
HIGH PERFORMANCE POLYMERS, 2021, 33 (03) :338-344
[49]   A review on self-assembly in microfluidic devices [J].
Dou, Yingying ;
Wang, Bingsheng ;
Jin, Mingliang ;
Yu, Ying ;
Zhou, Guofu ;
Shui, Lingling .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2017, 27 (11)
[50]   Modification of halloysite nanotubes with supramolecular self-assembly aggregates for reducing smoke release and fire hazard of polypropylene [J].
Shang, Sheng ;
Ma, Xiao ;
Yuan, Bihe ;
Chen, Gongqing ;
Sun, Yaru ;
Huang, Chuyuan ;
He, Song ;
Dai, Huaming ;
Chen, Xianfeng .
COMPOSITES PART B-ENGINEERING, 2019, 177