Synthesis and properties of π-extended donors with crown ether units

被引：2

作者：

Sako, K ^{[1
]}

Oku, H

Misaki, Y

Tanaka, K

Tatemitsu, H

机构：

[1] Nagoya Inst Technol, Dept Syst Management & Engn, Nagoya, Aichi 4668555, Japan

[2] Kyoto Univ, Dept Mol Engn, Kyoto 6068501, Japan

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

coupling reactions; electrochemical methods; UV-vis-NIR absorption; organic semiconductors based on conjugated molecules;

D O I：

10.1016/S0379-6779(02)01133-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We expect pi-extended donors that fused crown ether forming a stable complex with alkali metal functions as a molecular photonic switch. We synthesized new pi-extended donors incorporating a 2,5-bis(1,3-dithiol-2-yliden)-1,3,4,6-tetrathiapentalene (TTP) unit as a conductive site and crown ether units as metal binding sites. syntheses of new donors and results of their electrochemical and spectral properties will de discussed.

引用

页码：901 / 902

页数：2

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