Probing the influence O2 on photoinduced reversible electron transfer in perylenediimide-triphenylamine-based dendrimers by single-molecule spectroscopy

被引：36
作者：
Cotlet, M
Masuo, S
Lor, M
Fron, E
Van der Auweraer, M
Müllen, K
Hofkens, J [1 ]
De Schryver, F
机构：
[1] Katholieke Univ Leuven, Lab Photochem & Spect, B-3001 Heverlee, Belgium
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期
关键词：
dendrimers; electron transfer; fluorescence; spectroscopy; oxygen; single-molecule studies;
D O I：
10.1002/anie.200460560
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dynamics of reversible photoinduced electron transfer in individual perylene-diimide-triphenylamine-based donor-acceptor dendrimers immobilized in polystyrene were investigated by single-molecule spectroscopy. By changing the local concentration of oxygen, it was possible to influence the transition of the charge-separation state (CSS) either to the locally excited state (LES) or to the ground state (CS, see graphic).
引用
收藏
页码：6116 / 6120
页数：5
相关论文
共 22 条
  • [1] Probing conformational dynamics in single donor-acceptor synthetic molecules by means of photoinduced reversible electron transfer
    Cotlet, M
    Masuo, S
    Luo, GB
    Hofkens, J
    Van der Auweraer, M
    Verhoeven, J
    Müllen, K
    Xie, XLS
    De Schryver, F
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (40) : 14343 - 14348
  • [2] Identification of different emitting species in the red fluorescent protein DsRed by means of ensemble and single-molecule spectroscopy
    Cotlet, M
    Hofkens, J
    Habuchi, S
    Dirix, G
    Van Guyse, M
    Michiels, J
    Vanderleyden, J
    De Schryver, FC
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (25) : 14398 - 14403
  • [3] Spatially heterogeneous dynamics in supercooled liquids
    Ediger, MD
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2000, 51 : 99 - 128
  • [4] Conformational transitions monitored for single molecules in solution
    Edman, L
    Mets, U
    Rigler, R
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1996, 93 (13) : 6710 - 6715
  • [5] Monitoring conformational dynamics of a single molecule by selective fluorescence spectroscopy
    Eggeling, C
    Fries, JR
    Brand, L
    Günther, R
    Seidel, CAM
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1998, 95 (04) : 1556 - 1561
  • [6] Reversible intramolecular electron transfer at the single-molecule level
    Gronheid, R
    Stefan, A
    Cotlet, M
    Hofkens, J
    Qu, JQ
    Müllen, K
    Van der Auweraer, M
    Verhoeven, JW
    De Schryver, FC
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (35) : 4209 - 4214
  • [7] GRONHEID R, 2003, ANGEW CHEM, V115, P4341
  • [8] Probes for detection of specific DNA sequences at the single-molecule level
    Knemeyer, JP
    Marmé, N
    Sauer, M
    [J]. ANALYTICAL CHEMISTRY, 2000, 72 (16) : 3717 - 3724
  • [9] Single-molecule spectroscopy of intramolecular electron transfer in donor-bridge-acceptor systems
    Liu, RC
    Holman, MW
    Zang, L
    Adams, DM
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (34) : 6522 - 6526
  • [10] Photoinduced electron transfer in a rigid first generation triphenylamine core dendrimer substituted with a peryleneimide acceptor
    Lor, M
    Thielemans, J
    Viaene, L
    Cotlet, M
    Hofkens, J
    Weil, T
    Hampel, C
    Müllen, K
    Verhoeven, JW
    Van der Auweraer, M
    De Schryver, FC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) : 9918 - 9925
123