Electrochemical corrosion behavior of Al7075 rotating disc electrode in neutral solution containing l-glutamine as a green inhibitor

被引:23
作者
Ashassi-Sorkhabi, H. [1 ]
Asghari, E. [1 ]
机构
[1] Univ Tabriz, Fac Chem, Dept Phys Chem, Electrochem Res Lab, Tabriz, Iran
关键词
Hydrodynamic; Corrosion; Inhibition; Aluminum; Glutamine; MILD-STEEL; ALUMINUM-ALLOY; LOCALIZED CORROSION; 3-PERCENT NACL; PURE ALUMINUM; AMINO-ACIDS; SCHIFF-BASE; N80; STEEL; IMPEDANCE; CHLORIDE;
D O I
10.1007/s10800-009-0038-5
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This is a study of the electrochemical corrosion behavior of aluminum alloy Al7075 and its corrosion inhibition using l-glutamine in 3.5% NaCl solution under different hydrodynamic conditions. The hydrodynamic conditions were simulated by using a rotating disc electrode. The results showed that an increase in rotation speed leads to a higher corrosion current density, while the charge transfer resistance decreases and corrosion potential shifts toward more positive values. The inhibition efficiency depends on rotation speed. That is, the efficiency was low in stagnant solution, but enhanced significantly under hydrodynamic conditions. The phenomenon was attributed to the increased mass transport of inhibitor's molecules to the electrode surface that is advantageous for improvement of inhibition efficiency. However, higher rotation speeds (Omega a parts per thousand yen 1,500 rpm) cause a slight reduction of efficiency due to higher shear stresses.
引用
收藏
页码:631 / 637
页数:7
相关论文
共 49 条
  • [1] Ashassi-Sorkhabi H, 2000, ACTA CHIM SLOV, V47, P507
  • [2] The inhibition effect of some amino acids towards the corrosion of aluminum in 1 M HCl+1 M H2SO4 solution
    Ashassi-Sorkhabi, H
    Ghasemi, Z
    Seifzadeh, D
    [J]. APPLIED SURFACE SCIENCE, 2005, 249 (1-4) : 408 - 418
  • [3] Effect of hydrodynamic conditions on the inhibition performance of L-methionine as a "green" inhibitor
    Ashassi-Sorkhabi, H.
    Asghari, E.
    [J]. ELECTROCHIMICA ACTA, 2008, 54 (02) : 162 - 167
  • [4] Interactions of some Schiff base compounds with mild steel surface in hydrochloric acid solution
    Bayol, Emel
    Gurten, Tijen
    Gurten, A. Ali
    Erbil, Mehmet
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (02) : 624 - 630
  • [5] The corrosion inhibition of mild steel in acidic media by a new triazole derivative
    Bentiss, F
    Lagrenee, M
    Traisnel, M
    Hornez, JC
    [J]. CORROSION SCIENCE, 1999, 41 (04) : 789 - 803
  • [6] The inhibition effect of amino acids and hydroxy carboxylic acids on pitting corrosion of aluminum alloy 7075
    Bereket, G
    Yurt, A
    [J]. CORROSION SCIENCE, 2001, 43 (06) : 1179 - 1195
  • [7] AN EIS STUDY OF ALUMINUM BARRIER-TYPE OXIDE-FILMS FORMED IN DIFFERENT MEDIA
    BESSONE, JB
    SALINAS, DR
    MAYER, CE
    EBERT, M
    LORENZ, WJ
    [J]. ELECTROCHIMICA ACTA, 1992, 37 (12) : 2283 - 2290
  • [8] Electrochemical behavior and localized corrosion associated with Al7Cu2Fe particles in aluminum alloy 7075-T651
    Birbilis, N.
    Cavanaugh, M. K.
    Buchheit, R. G.
    [J]. CORROSION SCIENCE, 2006, 48 (12) : 4202 - 4215
  • [9] ADSORPTION OF NORMAL-DECYLAMINE ON SOLID METAL ELECTRODES
    BOCKRIS, JO
    SWINKELS, DAJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1964, 111 (06) : 736 - 743
  • [10] Impedance of a rotating disc electrode with a reversible reaction
    Boillot, M
    Didierjean, S
    Lapicque, F
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2004, 34 (12) : 1191 - 1197