Palladium-Catalyzed Aminocarbonylation of Aryl Halides with 2,4,6-Trichloro-1,3,5-triazine/Formamide Mixed Reagent

被引：14

作者：

Iranpoor, Nasser ^{[1
]}

Panahi, Farhad ^{[1
,2
]}

Roozbin, Fatemeh ^{[1
]}

Erfan, Soodabeh ^{[1
]}

Rahimi, Sajjad ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

[2] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, Tehran, Iran

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 09期

关键词：

Synthetic methods; Palladium; Amides; Amidation; MONOXIDE-FREE AMINOCARBONYLATION; CARBON-MONOXIDE; DIRECT CARBAMOYLATION; CYANURIC CHLORIDE; SITU GENERATION; CARBONYLATION; IODIDES; AMINES; MO(CO)(6); EFFICIENT;

D O I：

10.1002/ejoc.201501607

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this work, the mixture of formamide and 2,4,6-trichloro-1,3,5-triazine (cyanuric chloride or TCT) is introduced as a new amidating agent in Pd-catalyzed aminocarbonylation of aryl halides. In the presence of a catalytic amount of palladium and TCT/formamide reagent, a range of aryl halides (X = Cl, Br, I) were converted into amides efficiently in N, N-dimethylformamide at 120 degrees C.

引用

页码：1781 / 1787

页数：7

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