Bases and Basic Materials in Chemical and Environmental Processes. Liquid versus Solid Basicity

被引:180
作者
Busca, Guido [1 ]
机构
[1] Univ Genoa, Lab Chim Superfici & Catalisi Ind, Dipartimento Ingn Chim & Proc GB Bonino, I-16129 Genoa, Italy
关键词
X-RAY-DIFFRACTION; SKELETAL ISOMERIZATION CATALYSIS; UNCHARGED AUXILIARY BASES; SUPPORTED METAL-CATALYSTS; FT-IR CHARACTERIZATION; ION-EXCHANGE RESINS; SURFACE-PROPERTIES; CARBON-DIOXIDE; OXIDE CATALYSTS; MAGNESIUM-OXIDE;
D O I
10.1021/cr9000989
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A scientific review informed about the characteristics of basic compounds and materials used in industrial and technological chemistry. The review emphasized on the the properties of liquid bases, the characterization, and use of solid bases. The contribution was intended to emphasize the linkage between the chemical knowledge of acid-base interactions and the engineering of chemical processes, along with their environmental impact. It also provided evidence of trends aimed at improving process safety and limiting environmental pollution when they were related to the increased use of solid basic materials.
引用
收藏
页码:2217 / 2249
页数:33
相关论文
共 307 条
  • [21] Interaction of carbon dioxide with the surface of zirconia polymorphs
    Bachiller-Baeza, B
    Rodriguez-Ramos, I
    Guerrero-Ruiz, A
    [J]. LANGMUIR, 1998, 14 (13) : 3556 - 3564
  • [22] Baerlocher C., 2001, ATLAS ZEOLITE FRAMEW
  • [23] Baerns M., 1996, APPL CATAL A-GEN, V139, P107
  • [24] Structural changes and surface activities of ethylbenzene dehydrogenation catalysts during deactivation
    Baghalha, Morteza
    Ebrahimpour, Omid
    [J]. APPLIED CATALYSIS A-GENERAL, 2007, 326 (02) : 143 - 151
  • [25] Characterization of the structural and gas adsorption properties of ETS-10 molecular sieve
    Bagnasco, G
    Turco, M
    Busca, G
    Armaroli, T
    Nastro, A
    De Luca, P
    [J]. ADSORPTION SCIENCE & TECHNOLOGY, 2003, 21 (07) : 683 - 696
  • [26] A spectroscopy and catalysis study of the nature of active sites of MgO catalysts: Thermodynamic Bronsted basicity versus reactivity of basic sites
    Bailly, ML
    Chizallet, C
    Costentin, G
    Krafft, JM
    Lauron-Pernot, H
    Che, M
    [J]. JOURNAL OF CATALYSIS, 2005, 235 (02) : 413 - 422
  • [27] Bandosz TJ, 2006, INTERFACE SCI TECHNO, V7, P1
  • [28] SURFACE-ACTIVITY OF A BORON-NITRIDE POWDER - A VIBRATIONAL STUDY
    BARATON, MI
    MERLE, T
    QUINTARD, P
    LORENZELLI, V
    [J]. LANGMUIR, 1993, 9 (06) : 1486 - 1491
  • [29] NANOMETRIC BORON-NITRIDE POWDERS - LASER SYNTHESIS, CHARACTERIZATION AND FT-IR SURFACE STUDY
    BARATON, MI
    BOULANGER, L
    CAUCHETIER, M
    LORENZELLI, V
    LUCE, M
    MERLE, T
    QUINTARD, P
    ZHOU, YH
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1994, 13 (04) : 371 - 378
  • [30] Basic zeolites: Characterization and uses in adsorption and catalysis
    Barthomeuf, D
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1996, 38 (04): : 521 - 612