Bases and Basic Materials in Chemical and Environmental Processes. Liquid versus Solid Basicity

被引：180
作者：
Busca, Guido [1 ]
机构：
[1] Univ Genoa, Lab Chim Superfici & Catalisi Ind, Dipartimento Ingn Chim & Proc GB Bonino, I-16129 Genoa, Italy
来源：
CHEMICAL REVIEWS | 2010年 / 110卷 / 04期
关键词：
X-RAY-DIFFRACTION; SKELETAL ISOMERIZATION CATALYSIS; UNCHARGED AUXILIARY BASES; SUPPORTED METAL-CATALYSTS; FT-IR CHARACTERIZATION; ION-EXCHANGE RESINS; SURFACE-PROPERTIES; CARBON-DIOXIDE; OXIDE CATALYSTS; MAGNESIUM-OXIDE;
D O I：
10.1021/cr9000989
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A scientific review informed about the characteristics of basic compounds and materials used in industrial and technological chemistry. The review emphasized on the the properties of liquid bases, the characterization, and use of solid bases. The contribution was intended to emphasize the linkage between the chemical knowledge of acid-base interactions and the engineering of chemical processes, along with their environmental impact. It also provided evidence of trends aimed at improving process safety and limiting environmental pollution when they were related to the increased use of solid basic materials.
引用
收藏
页码：2217 / 2249
页数：33
相关论文
共 307 条
  • [1] Supported choline hydroxide (ionic liquid) as heterogeneous catalyst for aldol condensation reactions
    Abelló, S
    Medina, F
    Rodríguez, X
    Cesteros, Y
    Salagre, P
    Sueiras, JE
    Tichit, D
    Coq, B
    [J]. CHEMICAL COMMUNICATIONS, 2004, (09) : 1096 - 1097
  • [2] Analysis of the relationship between H2S removal capacity and surface properties of unimpregnated activated carbons
    Adib, F
    Bagreev, A
    Bandosz, TJ
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (04) : 686 - 692
  • [3] New Pd/Pt on Mg/Al basic mixed oxides for the hydrogenation and hydrogenolysis of naphthalene
    Albertazzi, S
    Busca, G
    Finocchio, E
    Glöckler, R
    Vaccari, A
    [J]. JOURNAL OF CATALYSIS, 2004, 223 (02) : 372 - 381
  • [4] Design of C2-chiral diamines that are computationally predicted to be a million-fold more basic than the original proton sponges
    Alder, RW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) : 7924 - 7931
  • [5] STRAIN EFFECTS ON AMINE BASICITIES
    ALDER, RW
    [J]. CHEMICAL REVIEWS, 1989, 89 (05) : 1215 - 1223
  • [6] REACTIVITY AND PHYSICOCHEMICAL CHARACTERIZATION OF V2O5-WO3/TIO2 DE-NOX CATALYSTS
    ALEMANY, LJ
    LIETTI, L
    FERLAZZO, N
    FORZATTI, P
    BUSCA, G
    GIAMELLO, E
    BREGANI, F
    [J]. JOURNAL OF CATALYSIS, 1995, 155 (01) : 117 - 130
  • [7] Alghamdi K., 2009, METAL OXIDE CATALYSI, V2, P819
  • [8] Microhydration of Cs+ ion:: A density functional theory study on Cs+-(H2O)n clusters (n=1-10)
    Ali, Sk. M.
    De, S.
    Maity, D. K.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (04)
  • [9] Preparation, characterization and surface structure of coprecipitated high-area SrxTiO2+x(0<=x<=1) powders
    Amores, JMG
    Escribano, VS
    DAturi, M
    Busca, G
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (05) : 879 - 886
  • [10] [Anonymous], 2002, Ullmann's Encyclopedia of Industrial Chemistry
12345678910